Iodine-catalyzed cross-coupling of isocyanides and thiols for the synthesis of S-thiocarbamates

被引：24
|
作者：
Pathare, Ramdas S. [1 ]
Patil, Vikas [2 ]
Kaur, Harpreet [3 ]
Maurya, Antim K. [4 ]
Agnihotri, Vijai K. [4 ]
Khan, Shahnawaz [5 ]
Devunuri, Nagaraju [2 ]
Sharon, Ashoke [3 ]
Sawant, Devesh M. [1 ]
机构：
[1] Cent Univ Rajasthan, Sch Chem Sci & Pharm, NH8, Ajmer 305817, Rajasthan, India
[2] Vignans Fdn Sci Technol & Res, Guntur 522213, Andhra Pradesh, India
[3] Birla Inst Technol, Dept Chem, Ranchi 835215, Jharkhand, India
[4] Inst Himalayan Bioresource Technol, CSIR, Nat Prod Chem & Proc Dev Div, Palampur 176061, Himachal Prades, India
[5] Bhupal Nobles Univ, Dept Chem, Udaipur 313001, Rajasthan, India
来源：
ORGANIC & BIOMOLECULAR CHEMISTRY | 2018年 / 16卷 / 37期
关键词：
C-H FUNCTIONALIZATION; ONE-POT SYNTHESIS; UREAS; CARBONYLATION; HERBICIDES; PARADIGM; ANILINES; ALKENES; SALTS; ARYL;
D O I：
10.1039/c8ob01855c
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel and efficient metal free, redox-neutral method for the synthesis of secondary thiocarbamates by cross-coupling of readily available thiophenol and isocyanides has been developed. The present methodology exhibits a broad substrate scope with good to excellent yields without an additive/extra oxidant under mild reaction conditions catalyzed by inexpensive iodine as the catalyst.
引用
收藏
页码：8263 / 8266
页数：4
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