CuO hollow nanosphere-catalyzed cross-coupling of aryl iodides with thiols

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作者
Hyunje Woo
Balaji Mohan
Eunjung Heo
Ji Chan Park
Hyunjoon Song
Kang Hyun Park
机构
[1] Pusan National University,Department of Chemistry and Chemistry Institute for Functional Materials
[2] Korea Institute of Energy Research,Clean Fuel Department
[3] Korea Advanced Institute of Science and Technology,Department of Chemistry
关键词
Microwave; Copper oxide; Acetylene black; Heterogeneous; Ullmann;
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摘要
New functionalized CuO hollow nanospheres on acetylene black (CuO/AB) and on charcoal (CuO/C) have been found to be effective catalysts for C-S bond formation under microwave irradiation. CuO catalysts showed high catalytic activity with a wide variety of substituents which include electron-rich and electron-poor aryl iodides with thiophenols by the addition of two equivalents of K2CO3 as base in the absence of ligands.
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