An Efficient Copper-Catalyzed Cross-Coupling Reaction of Thiols with Aryl Iodides

被引：49

作者：

Kao, Hsin-Lun ^{[1
]}

Chen, Chin-Keng ^{[1
]}

Wang, Yu-Jen ^{[1
]}

Lee, Chin-Fa ^{[1
]}

机构：

[1] Natl Chung Hsing Univ, Dept Chem, Taichung 402, Taiwan

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2011年 / 2011卷 / 09期

关键词：

Copper; Cross-coupling; Sulfur; Thioethers; Homogeneous catalysis; C-S; BOND FORMATION; NUCLEOPHILIC-SUBSTITUTION; BORONIC ACIDS; PALLADIUM; HALIDES; ARYLATION; LIGAND; COMPLEXES; SYSTEM;

D O I：

10.1002/ejoc.201001667

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Commercially available Cu2O powder is a very reactive catalyst for the coupling of thiols to aryl iodides. A variety of functional groups including esters, unprotected amines, alcohols, and heterocycles tolerate the reaction conditions. Moreover, di-ortho-substituted aryl iodides with sterically demanding substrates were also coupled to give the desired aryl thioethers in good to excellent yields.

引用

页码：1776 / 1781

页数：6

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