Iodine-catalyzed cross-coupling of isocyanides and thiols for the synthesis of S-thiocarbamates

被引：24

作者：

Pathare, Ramdas S. ^{[1
]}

Patil, Vikas ^{[2
]}

Kaur, Harpreet ^{[3
]}

Maurya, Antim K. ^{[4
]}

Agnihotri, Vijai K. ^{[4
]}

Khan, Shahnawaz ^{[5
]}

Devunuri, Nagaraju ^{[2
]}

Sharon, Ashoke ^{[3
]}

Sawant, Devesh M. ^{[1
]}

机构：

[1] Cent Univ Rajasthan, Sch Chem Sci & Pharm, NH8, Ajmer 305817, Rajasthan, India

[2] Vignans Fdn Sci Technol & Res, Guntur 522213, Andhra Pradesh, India

[3] Birla Inst Technol, Dept Chem, Ranchi 835215, Jharkhand, India

[4] Inst Himalayan Bioresource Technol, CSIR, Nat Prod Chem & Proc Dev Div, Palampur 176061, Himachal Prades, India

[5] Bhupal Nobles Univ, Dept Chem, Udaipur 313001, Rajasthan, India

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2018年 / 16卷 / 37期

关键词：

C-H FUNCTIONALIZATION; ONE-POT SYNTHESIS; UREAS; CARBONYLATION; HERBICIDES; PARADIGM; ANILINES; ALKENES; SALTS; ARYL;

D O I：

10.1039/c8ob01855c

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A novel and efficient metal free, redox-neutral method for the synthesis of secondary thiocarbamates by cross-coupling of readily available thiophenol and isocyanides has been developed. The present methodology exhibits a broad substrate scope with good to excellent yields without an additive/extra oxidant under mild reaction conditions catalyzed by inexpensive iodine as the catalyst.

引用

页码：8263 / 8266

页数：4

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