Iodine-catalyzed efficient 2-arylsulfanylphenol formation from thiols and cyclohexanones

被引：105
|
作者：
Liao, Yunfeng [1 ,2 ]
Jiang, Pengcheng [1 ]
Chen, Shanping [1 ]
Qi, Hongrui [1 ]
Deng, Guo-Jun [1 ]
机构：
[1] Xiangtan Univ, Coll Chem, Key Lab Environm Friendly Chem & Applicat, Minist Educ, Xiangtan 411105, Peoples R China
[2] Hunan Inst Engn, Sch Chem & Chem Engn, Xiangtan 411104, Peoples R China
来源：
GREEN CHEMISTRY | 2013年 / 15卷 / 12期
基金：
中国国家自然科学基金; 高等学校博士学科点专项科研基金;
关键词：
METAL-FREE SYNTHESIS; C-H BOND; ARYL HALIDES; AEROBIC DEHYDROGENATION; HIGHLY EFFICIENT; SULFUR; INDOLES; LIGAND; 3-SULFENYLATION; AROMATIZATION;
D O I：
10.1039/c3gc41671b
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A novel method for the formation of 2-arylsulfanylphenols from thiols and cyclohexanones is described. Iodine was used as an effective catalyst for this kind of transformation. Cyclohexanones were used as a phenol source via a dehydrogenation and tautomerization reaction.
引用
收藏
页码：3302 / 3306
页数：5
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