Palladium-Catalyzed Migratory Insertion of Isocyanides: An Emerging Platform in Cross-Coupling Chemistry

被引：395
|
作者：
Vlaar, Tjostil [1 ,2 ]
Ruijter, Eelco [1 ,2 ]
Maes, Bert U. W. [3 ]
Orru, Romano V. A. [1 ,2 ]
机构：
[1] Vrije Univ Amsterdam, Dept Chem & Pharmaceut Sci, NL-1081 HV Amsterdam, Netherlands
[2] Vrije Univ Amsterdam, AIMMS, NL-1081 HV Amsterdam, Netherlands
[3] Univ Antwerp, Dept Chem, B-2020 Antwerp, Belgium
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2013年 / 52卷 / 28期
关键词：
heterocycles; homogeneous catalysis; isocyanides; palladium; synthetic methods; TRANSITION-METAL-COMPLEXES; ARYL HALIDES; LIVING POLYMERIZATION; ISONITRILE INSERTION; SUCCESSIVE INSERTION; 3-COMPONENT REACTION; MULTIPLE INSERTION; CONCISE SYNTHESIS; ALLYL CYANAMIDES; BOND;
D O I：
10.1002/anie.201300942
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Isocyanides have been important building blocks in organic synthesis since the discovery of the Ugi reaction and related isocyanide-based multicomponent reactions. In the past decade isocyanides have found a new application as versatile C-1 building blocks in palladium catalysis. Palladium-catalyzed reactions involving isocyanide insertion offer a vast potential for the synthesis of nitrogen-containing fine chemicals. This Minireview discusses all the achievements in this emerging field.
引用
收藏
页码：7084 / 7097
页数：14
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