Quantification of Hydrogen in Natural Diamond by Secondary Ion Mass Spectrometry (SIMS)

被引：2

作者：

Kaminsky, F. V. ^{[1
]}

Shilobreeva, S. N. ^{[1
]}

Ber, B. Ya. ^{[2
]}

Kazantsev, D. Yu. ^{[2
]}

机构：

[1] Russian Acad Sci, Vernadsky Inst Geochem & Analyt Chem, Moscow 119991, Russia

[2] Russian Acad Sci, Ioffe Phys Tech Inst, St Petersburg 194021, Russia

来源：

DOKLADY EARTH SCIENCES | 2020年 / 494卷 / 01期

关键词：

diamond; hydrogen; secondary ion mass spectrometry;

D O I：

10.1134/S1028334X20090093

中图分类号：

P [天文学、地球科学];

学科分类号：

07 ;

摘要：

The volumetric concentration of hydrogen in two Brazilian diamonds is determined using secondary ion mass spectrometry and implantation of hydrogen into an external standard sample (with a dose of 1 x 16 at/cm(2)and energy of 120 KeV). The diamonds studied differ noticeably in their intensities of IR-active hydrogen from 0 to 1.5 cm(-1)according to the analyses of their IR spectra. The results demonstrate that for both samples studied, the volumetric concentration of hydrogen does not exceed the reached detectable level of (1-2) x 10(18)at/cm(3)or 1.7-3.3 at. ppm; i.e., it is lower by an order of magnitude than in the early chemical analysis and by 2-3 orders of magnitude lower than the results of the ion-beam spectrochemical, nuclear-physical, and ERDA analyses. Only a part of the hydrogen forms optically active impurities in diamond crystals and can be determined by spectral methods.

引用

页码：699 / 703

页数：5

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