Quantification of Hydrogen in Natural Diamond by Secondary Ion Mass Spectrometry (SIMS)

被引：2
|
作者：
Kaminsky, F. V. [1 ]
Shilobreeva, S. N. [1 ]
Ber, B. Ya. [2 ]
Kazantsev, D. Yu. [2 ]
机构：
[1] Russian Acad Sci, Vernadsky Inst Geochem & Analyt Chem, Moscow 119991, Russia
[2] Russian Acad Sci, Ioffe Phys Tech Inst, St Petersburg 194021, Russia
来源：
DOKLADY EARTH SCIENCES | 2020年 / 494卷 / 01期
关键词：
diamond; hydrogen; secondary ion mass spectrometry;
D O I：
10.1134/S1028334X20090093
中图分类号：
P [天文学、地球科学];
学科分类号：
07 ;
摘要：
The volumetric concentration of hydrogen in two Brazilian diamonds is determined using secondary ion mass spectrometry and implantation of hydrogen into an external standard sample (with a dose of 1 x 16 at/cm(2)and energy of 120 KeV). The diamonds studied differ noticeably in their intensities of IR-active hydrogen from 0 to 1.5 cm(-1)according to the analyses of their IR spectra. The results demonstrate that for both samples studied, the volumetric concentration of hydrogen does not exceed the reached detectable level of (1-2) x 10(18)at/cm(3)or 1.7-3.3 at. ppm; i.e., it is lower by an order of magnitude than in the early chemical analysis and by 2-3 orders of magnitude lower than the results of the ion-beam spectrochemical, nuclear-physical, and ERDA analyses. Only a part of the hydrogen forms optically active impurities in diamond crystals and can be determined by spectral methods.
引用
收藏
页码：699 / 703
页数：5
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