The structural properties and the energy gap of Si-C-N films deposited by PECVD method from hexamethyldisilazane in the temperature range of 200-700 degrees C were studied. The films were deposited on silicon and glass substrates that made it possible to perform the XRD analysis and study the absorption infrared (FTIR) and optical spectra. The deconvolution of main band by Gaussians indicates that the main contributions come from the vibrations of Si-C, Si-N and Si-O bonds. It is shown that an intensive effusion of hydrogen from the films occurs with increasing temperature. The band gap decreases from 2.3 to 1.6 eV as substrate temperature is changed from 200 to 700 degrees C.
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S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R ChinaS China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R China
Shi, Zhifeng
Wang, Yingjun
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S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R ChinaS China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R China
Wang, Yingjun
Du, Chang
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S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R ChinaS China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R China
Du, Chang
Huang, Nan
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SW Jiaotong Univ, Minist Educ, Key Lab Adv Technol Mat, Chengdu 610031, Peoples R ChinaS China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R China
Huang, Nan
Wang, Lin
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S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R ChinaS China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R China
Wang, Lin
Ning, Chengyun
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S China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R ChinaS China Univ Technol, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R China