Optical Properties of PECVD Si-C-N Films

被引:0
|
作者
Kozak, A. O. [1 ]
Ivashchenko, V. I. [1 ]
Porada, O. K. [1 ]
Ivashchenko, L. A. [1 ]
Malakhov, V. Ya [1 ]
Tomila, T. V. [1 ]
机构
[1] NAS Ukraine, Inst Problems Mat Sci, 3 Krzhyzhanovsky Str, UA-03142 Kiev, Ukraine
关键词
PECVD; Hexamethyldisilazane; Si-C-N films; FTIR; Optical spectra;
D O I
暂无
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The structural properties and the energy gap of Si-C-N films deposited by PECVD method from hexamethyldisilazane in the temperature range of 200-700 degrees C were studied. The films were deposited on silicon and glass substrates that made it possible to perform the XRD analysis and study the absorption infrared (FTIR) and optical spectra. The deconvolution of main band by Gaussians indicates that the main contributions come from the vibrations of Si-C, Si-N and Si-O bonds. It is shown that an intensive effusion of hydrogen from the films occurs with increasing temperature. The band gap decreases from 2.3 to 1.6 eV as substrate temperature is changed from 200 to 700 degrees C.
引用
收藏
页数:6
相关论文
共 50 条
  • [31] Nanodomain growth in amorphous Si-C-N
    Gruber, W.
    Starykov, O.
    Schmidt, H.
    PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS, 2009, 3 (2-3): : 85 - 87
  • [32] Microstructure, mechanical properties, and wetting behavior of Si-C-N thin films grown by reactive magnetron sputtering
    Berlind, T
    Hellgren, N
    Johansson, MP
    Hultman, L
    SURFACE & COATINGS TECHNOLOGY, 2001, 141 (2-3): : 145 - 155
  • [33] High temperature properties of polymer derived amorphous Si-C-N materials
    Konetschny, C
    Li, YL
    An, L
    Raj, R
    Butchereit, E
    Riedel, R
    HIGH TEMPERATURE MATERIALS CHEMISTRY, PTS I AND II, PROCEEDINGS, 2000, 15 : 387 - 390
  • [34] Correlation between electrical properties and composition/microstructure of Si-C-N ceramics
    Haluschka, C
    Engel, C
    Riedel, R
    Kleebe, HJ
    Franke, R
    ELECTRICALLY BASED MICROSTRUCTURAL CHARACTERIZATION II, 1998, 500 : 285 - 290
  • [35] Effects of substrate pretreatments and catalyst applications on Si-C-N films and nanotube formations
    Chang, Hui Lin
    Kuo, Cheng Tzu
    Japanese Journal of Applied Physics, Part 1: Regular Papers and Short Notes and Review Papers, 2001, 40 (12): : 7018 - 7022
  • [36] Effects of substrate pretreatments and catalyst applications on Si-C-N films and nanotube formations
    Chang, HL
    Kuo, CT
    JAPANESE JOURNAL OF APPLIED PHYSICS PART 1-REGULAR PAPERS SHORT NOTES & REVIEW PAPERS, 2001, 40 (12): : 7018 - 7022
  • [37] Structure analysis and properties of Si-C-N ceramics derived from polysilazanes
    Bill, J
    Seitz, J
    Thurn, G
    Durr, J
    Canel, J
    Janos, BZ
    Jalowiecki, A
    Sauter, D
    Schempp, S
    Lamparter, HP
    Mayer, J
    Aldinger, F
    PHYSICA STATUS SOLIDI A-APPLIED RESEARCH, 1998, 166 (01): : 269 - 296
  • [38] Balance the oxidation resistance and mechanical properties of C/Si-C-N composite by a Si-O-C interphase
    Lu, Guofeng
    Jiao, Gengsheng
    COMPOSITE INTERFACES, 2012, 19 (02) : 83 - 91
  • [39] Optical and structural characterization of laser-synthesized ultrafine Si-C-N powders
    Dohcevic, ZD
    Matovic, B
    Boskovic, S
    Popovic, ZV
    PHILOSOPHICAL MAGAZINE A-PHYSICS OF CONDENSED MATTER STRUCTURE DEFECTS AND MECHANICAL PROPERTIES, 2002, 82 (01): : 93 - 105
  • [40] Influence of carbon content and average energy of deposited ions on mechanical and optical properties of Si-C-N films grown by plasma ion immersion processing
    Afanasyev-Charkin, IV
    Nastasi, M
    JOURNAL OF VACUUM SCIENCE & TECHNOLOGY A, 2003, 21 (06): : 1909 - 1914