Optical Properties of PECVD Si-C-N Films

被引:0
|
作者
Kozak, A. O. [1 ]
Ivashchenko, V. I. [1 ]
Porada, O. K. [1 ]
Ivashchenko, L. A. [1 ]
Malakhov, V. Ya [1 ]
Tomila, T. V. [1 ]
机构
[1] NAS Ukraine, Inst Problems Mat Sci, 3 Krzhyzhanovsky Str, UA-03142 Kiev, Ukraine
关键词
PECVD; Hexamethyldisilazane; Si-C-N films; FTIR; Optical spectra;
D O I
暂无
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
The structural properties and the energy gap of Si-C-N films deposited by PECVD method from hexamethyldisilazane in the temperature range of 200-700 degrees C were studied. The films were deposited on silicon and glass substrates that made it possible to perform the XRD analysis and study the absorption infrared (FTIR) and optical spectra. The deconvolution of main band by Gaussians indicates that the main contributions come from the vibrations of Si-C, Si-N and Si-O bonds. It is shown that an intensive effusion of hydrogen from the films occurs with increasing temperature. The band gap decreases from 2.3 to 1.6 eV as substrate temperature is changed from 200 to 700 degrees C.
引用
收藏
页数:6
相关论文
共 50 条
  • [41] Mechanical and field emission properties of CGed Si(C,N) films synthesized by PECVD from HMDS precursor
    Li, Y. S.
    Kiyono, H.
    Shimada, S.
    Lu, X.
    Hirose, A.
    DIAMOND AND RELATED MATERIALS, 2006, 15 (10) : 1727 - 1731
  • [42] Fabrication and oxidation behavior of C/Si-C-N composite
    Lu, Guo-Feng
    Qiao, Sheng-Ru
    Gong, Man-Feng
    Hou, Jun-Tao
    Jiao, Geng-Sheng
    Cailiao Gongcheng/Journal of Materials Engineering, 2010, (03): : 13 - 17
  • [43] Formation of the Si-C-N nanorod in polymer matrix
    Luo, Yongming
    Zheng, Zhimin
    Xu, Caihong
    Xie, Zemin
    Zhang, Zhijie
    MATERIALS SCIENCE AND ENGINEERING A-STRUCTURAL MATERIALS PROPERTIES MICROSTRUCTURE AND PROCESSING, 2006, 432 (1-2): : 69 - 70
  • [44] SYNTHESIS OF ORGANOSILICON COMPOUNDS WITH A SI-C-N BOND
    LOSEV, VB
    BORISOV, MF
    JOURNAL OF GENERAL CHEMISTRY USSR, 1963, 33 (01): : 250 - &
  • [45] Structural, optical and electrical characterizations of μc-Si:H films deposited by PECVD
    Ambrosone, G
    Coscia, U
    Murri, R
    Pinto, N
    Ficcadenti, M
    Morresi, L
    SOLAR ENERGY MATERIALS AND SOLAR CELLS, 2005, 87 (1-4) : 375 - 386
  • [46] Effect of gas pressure on the optical properties of n-type a-Si:H thin films deposited by PECVD
    Li, Wei
    Chen, Yu-Xiang
    Jin, Xin
    Jiang, Yu-Peng
    Yang, Guang
    Jiang, Ya-Dong
    Dianzi Keji Daxue Xuebao/Journal of the University of Electronic Science and Technology of China, 2009, 38 (05): : 730 - 733
  • [47] Mechanical behavior related to various bonding states in amorphous Si-C-N hard films
    Zhuang, Chunqiang
    Schlemper, Christoph
    Fuchs, Regina
    Zhang, Lei
    Huang, Nan
    Vogel, Michael
    Staedler, Thorsten
    Jiang, Xin
    SURFACE & COATINGS TECHNOLOGY, 2014, 258 : 353 - 358
  • [48] Nanocrystalline Si3N4 with Si-C-N shell structure
    Junmin, X
    Wang, J
    MATERIALS LETTERS, 2001, 49 (06) : 318 - 323
  • [49] Effect of nitrogen gas flow on amorphous Si-C-N films produced by PVD techniques
    Moura, C
    Cunha, L
    Orfao, H
    Pischow, K
    De Rijk, J
    Rybinski, M
    Mrzyk, D
    SURFACE & COATINGS TECHNOLOGY, 2003, 174 : 324 - 330
  • [50] A comparative study of Si-C-N films on different substrates grown by RF magnetron sputtering
    Bhattacharyya, A. S.
    Mishra, S. K.
    Mukherjee, S.
    Das, G. C.
    JOURNAL OF ALLOYS AND COMPOUNDS, 2009, 478 (1-2) : 474 - 478