New inorganic ligand μ3-[SbO(H2O)2]3− in tetrahedral mixed-ligand rhenium cluster complexes K5[{Re4Q3[SbO(H2O)2]}(CN)12] (Q = S, Se)

被引：0
|
作者：
A. S. Pronin
Y. V. Mironov
机构：
[1] Siberian Branch of the Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry
来源：
Russian Chemical Bulletin | 2022年 / 71卷
关键词：
rhenium; chalcogen; antimony; cyanide; crystal structure; tetrahedral cluster complexes;
D O I：
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学科分类号：
摘要：
The mixed-ligand cluster complexes of the composition K5[{Re4S3[SbO(H2O)2]}-(CN)12]·8H2O (1) and K5[{Re4Se3[SbO(H2O)2]}(CN)12] · 3H2O (2) bearing the new inorganic ligand μ3-[SbO(H2O)2]3− were synthesized by the high-temperature reactions of ReI3 with Sb, S, or Se and KCN followed by the recrystallization of the soluble products from water. The structures of the new compounds were studied by X-ray diffraction analysis. Using mass spectrometry data, it was found that the μ3-[SbO(H2O)2]3− ligand is deprotonated stibine oxide, which is additionally coordinated by two water molecules.
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页码：2179 / 2186
页数：7
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