New inorganic ligand μ3-[SbO(H2O)2]3− in tetrahedral mixed-ligand rhenium cluster complexes K5[{Re4Q3[SbO(H2O)2]}(CN)12] (Q = S, Se)

被引：0

作者：

A. S. Pronin

Y. V. Mironov

机构：

[1] Siberian Branch of the Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry

来源：

Russian Chemical Bulletin | 2022年 / 71卷

关键词：

rhenium; chalcogen; antimony; cyanide; crystal structure; tetrahedral cluster complexes;

D O I：

暂无

中图分类号：

学科分类号：

摘要：

The mixed-ligand cluster complexes of the composition K5[{Re4S3[SbO(H2O)2]}-(CN)12]·8H2O (1) and K5[{Re4Se3[SbO(H2O)2]}(CN)12] · 3H2O (2) bearing the new inorganic ligand μ3-[SbO(H2O)2]3− were synthesized by the high-temperature reactions of ReI3 with Sb, S, or Se and KCN followed by the recrystallization of the soluble products from water. The structures of the new compounds were studied by X-ray diffraction analysis. Using mass spectrometry data, it was found that the μ3-[SbO(H2O)2]3− ligand is deprotonated stibine oxide, which is additionally coordinated by two water molecules.

引用

页码：2179 / 2186

页数：7

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