Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re4As3Q}5+ (Q = S, Se) and {Re4As2S2}6+

被引：10
|
作者：
Pronin, Aleksei S. [1 ]
Gayfulin, Yakov M. [1 ]
Smolentsev, Anton I. [1 ,2 ]
Mironov, Yuri V. [1 ,2 ]
机构：
[1] SB RAS, Nikolaev Inst Inorgan Chem, 3 Acad Lavrentiev Ave, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, 2 Pirogova Str, Novosibirsk 630090, Russia
来源：
JOURNAL OF CLUSTER SCIENCE | 2019年 / 30卷 / 05期
基金：
俄罗斯科学基金会;
关键词：
Heteroligand cluster; Arsenic; Chalcogen; Cyanometallate; Crystal structure;
D O I：
10.1007/s10876-019-01566-z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A high-temperature reactions of equimolar amounts of ReI3, As and S or Se with KCN following by recrystallization of the soluble products from water led to the formation of new cyanometallate cluster complexes K-7[{Re4As3S}(CN)(12)]center dot 10H(2)O (1) and K-7[{Re4As3Se}(CN)(12)]center dot 9.5H(2)O (2), respectively. Involvement of As2S3 instead of the mixture of As and S resulted in the formation of a cluster complex K-6[{Re4As2S2}(CN)(12)]center dot 3.5H(2)O (3). Crystal structures of the obtained compounds were investigated by the X-ray diffraction analysis. It was found that compounds 1-3 contain a new cubane cluster cores composed of the rhenium tetrahedron surrounded by the mu(3)-As and mu(3)-Q (Q = S, Se) ligands.
引用
收藏
页码：1253 / 1257
页数：5
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