One-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re4(µ3-Q)4}(CN)12]4− (Q = S, Se, Te) using ReI3

被引：0
|
作者：
A. S. Pronin
A. I. Smolentsev
Y. V. Mironov
机构：
[1] Siberian Branch of the Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry
[2] Novosibirsk State University,undefined
来源：
Russian Chemical Bulletin | 2019年 / 68卷
关键词：
rhenium; chalcogen; crystal structure; tetrahedral cluster complexes;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new method is proposed for the one-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re4(µ3-Q)4}(CN)12]4− (Q = S, Se, Te) using rhenium(iii) iodide as the starting compound. A cluster complex of the composition K4[{Re4S4}(CN)12]•H2O was synthesized for the first time and characterized by X-ray diffraction.
引用
收藏
页码：777 / 781
页数：4
相关论文
共 50 条
  • [1] One-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re4(μ3-Q)4}(CN)12]4- (Q = S, Se, Te) using ReI3
    Pronin, A. S.
    Smolentsev, A., I
    Mironov, Y., V
    RUSSIAN CHEMICAL BULLETIN, 2019, 68 (04) : 777 - 781
  • [2] New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re6(μ3-Q)8}(CN)6]4– (Q = S, Se, Te)
    A. S. Pronin
    S. S. Yarovoy
    A. I. Smolentsev
    Yu. V. Mironov
    Russian Journal of Coordination Chemistry, 2019, 45 : 119 - 123
  • [3] New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re6(3-Q)8}(CN)6]4- (Q = S, Se, Te)
    Pronin, A. S.
    Yarovoy, S. S.
    Smolentsev, A., I
    Mironov, Yu, V
    RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2019, 45 (02) : 119 - 123
  • [4] Synthesis and structures of new compounds based on tetrahedral rhenium chalcocyanide cluster anions [Re4Q4(CN)12]4− (Q = S or Se) and [Cu(bipy)2]2+ cations
    O. A. Efremova
    Yu. V. Mironov
    N. V. Kuratieva
    V. E. Fedorov
    Russian Chemical Bulletin, 2006, 55 : 1946 - 1949
  • [5] Synthesis and structures of new compounds based on tetrahedral rhenium chalcocyanide cluster anions [Re4Q4(CN)12]4- (Q = S or Se) and [Cu(bipy)2]2+ cations
    Efremova, O. A.
    Mironov, Yu. V.
    Kuratieva, N. V.
    Fedorov, V. E.
    RUSSIAN CHEMICAL BULLETIN, 2006, 55 (11) : 1946 - 1949
  • [6] Tetrahedral chalcogeno thiocyanate cluster complexes [Re4Q4(SCN)12]4- (Q= S, Se, Te):: synthesis and crystal structures
    Mironov, YV
    POLYHEDRON, 2000, 19 (04) : 437 - 439
  • [7] Singlet Oxygen Production and Biological Activity of Hexanuclear Chalcocyanide Rhenium Cluster Complexes [{Re6Q8}(CN)6]4- (Q = S, Se, Te)
    Solovieva, Anastasiya O.
    Kirakci, Kaplan
    Ivanov, Anton A.
    Kubat, Pavel
    Poznaogova, Tatiana N.
    Miroshnichenko, Svetlana M.
    Vorontsova, Elena V.
    Chechushkov, Anton V.
    Trifonova, Kristina E.
    Fufaeva, Maria S.
    Kretov, Evgeniy I.
    Mironov, Yuri V.
    Poveshchenko, Alexander F.
    Lang, Kamil
    Shestopalov, Michael A.
    INORGANIC CHEMISTRY, 2017, 56 (21) : 13491 - 13499
  • [8] RE4S4TE4 - A NEW MIXED RHENIUM CHALCOGENIDE CONTAINING A TETRAHEDRAL RE4 CLUSTER
    FEDOROV, VE
    MIRONOV, YV
    FEDIN, VP
    MIRONOV, YI
    JOURNAL OF STRUCTURAL CHEMISTRY, 1994, 35 (01) : 146 - 147
  • [9] Strained bonds in [Re4Q4X12]4− cluster complexes (Q = S, Se, Te; X = F, CN−) according to AIM and ELF data
    M. R. Ryzhikov
    S. G. Kozlova
    S. P. Gabuda
    Journal of Structural Chemistry, 2008, 49 : 587 - 594
  • [10] Tetrahedral Rhenium Cluster Complexes with Mixed-Ligand Cores {Re4As3Q}5+ (Q = S, Se) and {Re4As2S2}6+
    Aleksei S. Pronin
    Yakov M. Gayfulin
    Anton I. Smolentsev
    Yuri V. Mironov
    Journal of Cluster Science, 2019, 30 : 1253 - 1257
12345