Strained bonds in [Re4Q4X12]4− cluster complexes (Q = S, Se, Te; X = F, CN−) according to AIM and ELF data

被引：0
|
作者：
M. R. Ryzhikov
S. G. Kozlova
S. P. Gabuda
机构：
[1] Russian Academy of Sciences,A. V. Nikolaev Institute of Inorganic Chemistry, Siberian Division
[2] Russian Academy of Sciences,G. K. Boreskov Institute of Catalysis, Siberian Division
来源：
Journal of Structural Chemistry | 2008年 / 49卷
关键词：
AIM; ELF; cluster complexes; strained bonds;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
The electron density distribution in [Re4Q4X12]4− cubane-like clusters (Q = S, Se, Te; X = F, CN) was investigated by the AIM and ELF topological quantum-chemical methods. The Re-Re, Re-Q, and Re-X interatomic interactions are characterized by bcp type critical binding points and are strained.
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页码：587 / 594
页数：7
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