Synthesis and structures of new compounds based on tetrahedral rhenium chalcocyanide cluster anions [Re4Q4(CN)12]4- (Q = S or Se) and [Cu(bipy)2]2+ cations

被引：4
|
作者：
Efremova, O. A. [1 ]
Mironov, Yu. V. [1 ]
Kuratieva, N. V. [1 ]
Fedorov, V. E. [1 ]
机构：
[1] Russian Acad Sci, AV Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
来源：
RUSSIAN CHEMICAL BULLETIN | 2006年 / 55卷 / 11期
基金：
俄罗斯基础研究基金会;
关键词：
rhenium; tetrahedral chalcocyanide clusters; copper; cyanide bridges; 2,2 '-bipyridyl; crystal structure;
D O I：
10.1007/s11172-006-0535-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The reactions of the rhenium chalcocyanide cluster salts K-4[Re(4)Q(4)(CN)(12)]center dot 6H(2)O (Q = S or Se) with Cu2+ cations coordinated by the bidentate ligand 2,2'-bipyridyl (bipy) produced two new cluster compounds, [Cu(NH3)(bipy)(2)](2)[Re4S4(CN)(12)]center dot bipy center dot 3.25H(2)O (1) and [{Cu(bipy)(2)}(2)Re4Se4(CN)(12)]center dot bipy center dot 8.5H(2)O (2). The structures of these complexes were solved by X-ray diffraction. Compound 1 is ionic. Compound 2 is molecular. In the structures of both compounds, there are staking interactions between the {Cu(bipy)(2)}(2) cationic moieties and the solvate 2,2'-bipyridyl molecules.
引用
收藏
页码：1946 / 1949
页数：4
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