One-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re4(µ3-Q)4}(CN)12]4− (Q = S, Se, Te) using ReI3

被引：0
|
作者：
A. S. Pronin
A. I. Smolentsev
Y. V. Mironov
机构：
[1] Siberian Branch of the Russian Academy of Sciences,Nikolaev Institute of Inorganic Chemistry
[2] Novosibirsk State University,undefined
来源：
Russian Chemical Bulletin | 2019年 / 68卷
关键词：
rhenium; chalcogen; crystal structure; tetrahedral cluster complexes;
D O I：
暂无
中图分类号：
学科分类号：
摘要：
A new method is proposed for the one-step synthesis of tetrahedral rhenium chalcocyanide cluster complexes [{Re4(µ3-Q)4}(CN)12]4− (Q = S, Se, Te) using rhenium(iii) iodide as the starting compound. A cluster complex of the composition K4[{Re4S4}(CN)12]•H2O was synthesized for the first time and characterized by X-ray diffraction.
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页码：777 / 781
页数：4
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