Framework polymers based on octahedral chalcocyanide cluster [Re6Q8(CN)6]4-/3- anions (Q = Se, Te) and [Nd(Bipy)n]3+ complexes (n = 1, 2)

被引：15
|
作者：
Tarasenko, M. S. [1 ]
Naumov, N. G. [1 ]
Naumov, D. Yu. [1 ]
Kuratieva, N. V. [1 ]
Fedorov, V. E. [1 ]
机构：
[1] Russian Acad Sci, Inst Inorgan Chem, Siberian Div, Novosibirsk 630090, Russia
来源：
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY | 2006年 / 32卷 / 07期
关键词：
D O I：
10.1134/S1070328406070062
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Interaction of salts of the cluster anions {Re [Re(6)Q(8)(CN)(6)](4-/3-) (Q = Se, Te) with Nd salts in the presence of 2,2'-bipyridyl (Bipy) ligand brings about new coordination polymers: Pr-4(n) N[{Nd(Bipy)(H2O)(4)} (Re6Se8(CN)(6)}] center dot 2H(2)O (I) (space group C2/c, a = 18.2918(16) angstrom, b = 14.9972(13) angstrom, c = 37.513(3) angstrom, beta = 102.046(4)degrees, V = 10064.2(15) angstrom(3), Z = 8), [{Nd(Bipy)(2)(H2O)}{Re6Se8(CN)(6)}] (II) (space group C2/c, a = 15.8668(3) angstrom, b = 13.5403(3) angstrom, c = 20.5189(4) angstrom, beta = 110. 135(1)degrees, V = 4138.89(15) angstrom(3), Z = 4), and [{Nd(Bipy)(EtOH)(H2O)(4)} {Re6Te8(CN)(6)}] center dot EtOH (III) (space group P (1) over bar, a = 9.4733(6) angstrom, b = 12.5326(8) angstrom, c = 17.2374(11) angstrom, alpha = 96.561(2)degrees, beta = 90.310(2)degrees, gamma = 94.876(2)degrees, V = 4138.89(15) angstrom(3), Z = 4). The compounds synthesized are characterized by single-crystal X-ray diffraction and IR methods. Compounds I and III have layered (2D) structures, compound II is a framework (3D) polymer.
引用
收藏
页码：494 / 503
页数：10
相关论文
共 50 条
  • [1] Framework polymers based on octahedral chalcocyanide cluster [Re6Q8(CN)6]4−/3− anions (Q = Se, Te) and [Nd(Bipy)n]3+ Complexes (n = 1, 2)
    M. S. Tarasenko
    N. G. Naumov
    D. Yu. Naumov
    N. V. Kuratieva
    V. E. Fedorov
    [J]. Russian Journal of Coordination Chemistry, 2006, 32 : 494 - 503
  • [2] Electronic state of rhenium complexes with octahedral chalcocyanide cluster anions [Re6Q8(CN)6]3- (Q=S, Se, Te).: EPR and magnetic susceptibility studies
    Larina, TV
    Ikorskii, VN
    Vasenin, NT
    Anufrienko, VF
    Naumov, NG
    Ostanina, EV
    Fedorov, VE
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2002, 28 (08) : 554 - 556
  • [3] Electronic State of Rhenium Complexes with Octahedral Chalcocyanide Cluster Anions [Re6Q8(CN)6]3– (Q = S, Se, Te). EPR and Magnetic Susceptibility Studies
    T. V. Larina
    V. N. Ikorskii
    N. T. Vasenin
    V. F. Anufrienko
    N. G. Naumov
    E. V. Ostanina
    V. E. Fedorov
    [J]. Russian Journal of Coordination Chemistry, 2002, 28 : 554 - 556
  • [4] Mesolamellar phases containing [Re6Q8(CN)6]4- (Q = Te, Se, S) cluster anions
    Suh, Min-Jung
    Vien, Vo
    Huh, Seong
    Kim, Youngmee
    Kim, Sung-Jin
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2008, (05) : 686 - 692
  • [5] New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re6(3-Q)8}(CN)6]4- (Q = S, Se, Te)
    Pronin, A. S.
    Yarovoy, S. S.
    Smolentsev, A., I
    Mironov, Yu, V
    [J]. RUSSIAN JOURNAL OF COORDINATION CHEMISTRY, 2019, 45 (02) : 119 - 123
  • [6] Singlet Oxygen Production and Biological Activity of Hexanuclear Chalcocyanide Rhenium Cluster Complexes [{Re6Q8}(CN)6]4- (Q = S, Se, Te)
    Solovieva, Anastasiya O.
    Kirakci, Kaplan
    Ivanov, Anton A.
    Kubat, Pavel
    Poznaogova, Tatiana N.
    Miroshnichenko, Svetlana M.
    Vorontsova, Elena V.
    Chechushkov, Anton V.
    Trifonova, Kristina E.
    Fufaeva, Maria S.
    Kretov, Evgeniy I.
    Mironov, Yuri V.
    Poveshchenko, Alexander F.
    Lang, Kamil
    Shestopalov, Michael A.
    [J]. INORGANIC CHEMISTRY, 2017, 56 (21) : 13491 - 13499
  • [7] New Method for the Synthesis of Octahedral Rhenium Chalcocyanide Cluster Complexes [{Re6(μ3-Q)8}(CN)6]4– (Q = S, Se, Te)
    A. S. Pronin
    S. S. Yarovoy
    A. I. Smolentsev
    Yu. V. Mironov
    [J]. Russian Journal of Coordination Chemistry, 2019, 45 : 119 - 123
  • [8] Octahedral hexahydroxo rhenium cluster complexes [Re6Q8(OH)6]4-•: (Q = S, Se):: Aynthesis, structure, and properties
    Yarovoi, SS
    Mironov, YV
    Naumov, DY
    Gatilov, YV
    Kozova, SG
    Kim, SJ
    Fedorov, VE
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2005, (19) : 3945 - 3949
  • [9] Novel compounds based on [Re6Q8(L)6]4- (Q = S, Se, Te; L = CN, OH) and their applications
    Kim, Youngmee
    Fedorov, Vladimir E.
    Kim, Sung-Jin
    [J]. JOURNAL OF MATERIALS CHEMISTRY, 2009, 19 (39) : 7178 - 7190
  • [10] The first coordination polymers based on octahedral hexahydroxo rhenium cluster complexes [Re6Q8(OH)6]4- (Q = S, Se) and alkaline earth metal cations
    Mironov, YV
    Fedorov, VE
    Bang, HJ
    Kim, SJ
    [J]. EUROPEAN JOURNAL OF INORGANIC CHEMISTRY, 2006, (03) : 553 - 557
12345