Octahedral aqua fluoride rhenium cluster complexes K[Re6S8F3(H2O)3]•7H2O, H3O[Re6Se8F3(H2O)3]•7H2O and [Re6Q8F2(H2O)4]•12H2O (Q = S, Se):: Synthesis and structure

被引：12
|
作者：
Mironov, Yuri V.
Yarovoi, Spartak S.
Naumov, Dmitrii Y.
Simon, Arndt
Fedorov, Vladimir E.
机构：
[1] Russian Acad Sci, Nikolaev Inst Inorgan Chem, Siberian Branch, Novosibirsk 630090, Russia
[2] Max Planck Inst Festkorperforsch, D-707569 Stuttgart, Germany
来源：
INORGANICA CHIMICA ACTA | 2007年 / 360卷 / 09期
基金：
俄罗斯基础研究基金会;
关键词：
rhenium octahedral clusters; aqua fluoride complexes; synthesis; crystal structure;
D O I：
10.1016/j.ica.2007.02.012
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Four new octahedral cluster complexes-K[Re6S8F3(H2O)(3)]center dot 7H(2)O (1), H3O[Re6Se8F3(H2O)(3)]center dot-7H(2)O (2) and [Re(6)Q(8)F(2)(H2O)(4)]center dot 12H(2)O (Q=S (3), Se (4)), have been synthesized using the reaction of rhenium chalcobromide complexes K-4[Re6S8Br6]center dot 2H(2)O and Cs-3[Re6Se8Br6]center dot H2O with molten KHF2 and further crystallization form aqueous solutions under different conditions. All compounds synthesized were characterized by X-ray single-crystal diffraction, chemical analysis, and IR spectra. (C) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：2953 / 2957
页数：5
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