Synthesis, crystal structure of mixed-ligand complexes [Ni(NPA)2(Phen)(Ac)(H2O)]•H2O

被引：0

作者：

Kung Yun-Fei ^{[1
]}

Chen Zhi-Min ^{[1
]}

Li Dong-Ping ^{[1
]}

Kuang Dai-Zhi ^{[1
]}

机构：

[1] Hengyang Normal Univ, Dept Chem, Hengyang 421008, Hunan, Peoples R China

来源：

CHINESE JOURNAL OF INORGANIC CHEMISTRY | 2007年 / 23卷 / 10期

关键词：

nikcle(II) complex; N-phenylanthranilie acid; crystal structure; pi-pi aromatic interactions;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

hhA Nickle(II) complex [Ni(NPA)(2)(Phcn)(Ac)(H2O) center dot H2O has been synthesized (NPA=N-phenylanthranilic acid, Phen=1,10-phenanthroline and Ac=acetate) and characterized by IR, elemental analysis and X-ray crystal structure determination. It crystallizes in triclinic system, space group P1 with a=0.891 25(2) nm, b=1.451 85(3) rim, c=11.48554(3) nm, alpha=67.384(1)degrees, beta=82.932(1)degrees, gamma=85.168(1)degrees, V=1.759 50(6) nm(3), Z=2, D-c=1.405 g center dot cm(-3), F(000) =778, R-1=0.032 3, wR =0.084 7. The crystal structure shows that the Nikcle(II) ion is coordinated with two oxygen atoms from two N-phenylanthranilic acid, two nitrogen atoms from one 1,10-phenanthroline, two oxygen atoms from one acetate and one water respectively, forming a distorted octahedral coordination geometry.

引用

页码：1777 / 1780

页数：4

共 12 条

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