Synthetic, spectroscopic, and structural studies of bis(2-methyl-4phenylpentadienyl)ruthenium, Ru(2-CH3-4-C6H5C5H5)2:: characterization of isomeric open ruthenocenes

被引：5

作者：

Turpin, GC

Rheingold, AL ^{[1
]}

Ernst, RD

机构：

[1] Univ Delaware, Dept Chem, Newark, DE 19716 USA

[2] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 672卷 / 1-2期

关键词：

ruthenium complexes; diastereomers; structural studies; pentadienyl complexes;

D O I：

10.1016/S0022-328X(03)00149-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ru(2-methyl-4-phenylpentadienyl), has been isolated from the reaction of ruthenium chloride complexes with the appropriate diene and zinc metal in ethanol. The complex exists as a pair of diastereomers, which could be readily separated due to their significantly different solubilities. Structural studies reveal, as expected, that one of the isomers exists in the C-1 point group, while the other possesses (noncrystallographic) C-2 symmetry. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：109 / 114

页数：6

共 50 条

[21] Synthesis and photolysis of [M(CO)3H]2(η5,η5-C5H4CH2C5H4), where M = Mo and W.: Photochemical 'twist' rearrangement of M2(CO)6 (η5,η5-C5H4CH2C5H4) to give [M(CO)3][M(CO)3H](η5,η5:η1-C5H4CH2C5H3), where M = Mo and W.: The molecular structure [Mo(CO)3][Mo(CO)3Cl](η5,η5:η1-C5H4CH2C5H3)
Bitterwolf, TE
Saygh, A
Haener, JL
Fierro, R
Shade, JE
Rheingold, AL
Liable-Sands, L
Alt, HG
INORGANICA CHIMICA ACTA, 2002, 334 : 54 - 58
[22] [{(C(5)Me(4)H)Fe(C(5)Me(4))CH2C5H4}2Fe](2+).-[-2(CN)(4)](-).[C-3(CN)(5)](-)
Barlow, S
OHare, D
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 578 - 581
[23] CRYSTAL AND MOLECULAR STRUCTURES OF η~4-OLEFIN CARBENE COMPLEX[(η~4—C6H5CH=CH(?)CH(C6H4CH3—m)N(C6H5) C(OC2H5)=]Fe(CO)2·1/2C6H5·CH3
张泽莹
唐有祺
殷建国
陈家碧
徐维华
Science Bulletin, 1988, (17) : 1431 - 1435
[24] [RU(ETA(5)-C5H5)(ETA(4)-C5H4O)(AS(CH3)(3))]PF6 AND [RU(ETA(5)-C5H5)(ETA(4)-C5H4O)-(AS(C6H5)(3))]PF6
KIRCHNER, K
SCHMID, R
MEREITER, K
ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1995, 51 (pt 3) : 361 - 364
[25] Synthesis, characterization of [{(N-methyl-N-benzyl)amino}methyl]-ferrocenes and their cyclopalladated complexes:: Crystal structure of σ-Pd[(η5-C5H5)Fe(η5-C5H3CH2N(CH3)CH2C6H4NO2-4)]Cl(PPh3)
Wang, Hong-Xing
Wu, Hong-Fei
Zhou, Hui-Chao
Geng, Feng-Ying
Gao, Ren-Qing
Yang, Xiao-Li
Wan, Li
Zhang, Wen-Qin
Jin, Rong
INORGANICA CHIMICA ACTA, 2006, 359 (12) : 4114 - 4120
[26] FRIEDEL-CRAFTS CYNICHRODENOYLATION OF (CO)2(NO)CR(ETA-5-C5H4)CH2(ETA-5-C5H4)FE(ETA-5-C5H5) AND X-RAY STRUCTURES OF (CO)2(NO)CR(ETA-5-C5H4)CH2(ETA-5-C5H4)FE(ETA-5-C5H4)FE(ETA-5-C5H4)C(O)(ETA-5-C5H4)CR(CO)2(NO) AND (CO)2(NO)CR(ETA-5-C5H4)CH2(ETA-5-(2-C(O)-[(ETA-5-C5H4)CR(CO)2(NO)])C5H3)-FE(ETA-5-C5H5)
WANG, YP
HWU, JM
WANG, SL
WU, YJ
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1991, 414 (01) : 33 - 48
[27] STRUCTURE OF BIS(TRIPHENYLPHOSPHINE)BIS(PI-ALLYL)RUTHENIUM, (C3H5)2RU[P(C6H5)3]2
SMITH, AE
INORGANIC CHEMISTRY, 1972, 11 (10) : 2306 - &
[28] Synthesis and structure characterization of [HgCl(η5-C5H3C(CH3)=N-3C5H4N)Fe(η5-C5H5)]•1/2CH2Cl2
Lin, KH
Song, MP
Du, CX
Zhang, QH
Hao, XQ
Wu, YJ
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2004, 23 (01) : 15 - 18
[29] Synthesis and solid-state structure of [(η2:η5-C5Me4CH2CH2CH = CH2)Ru(η3-C3H5)]
Castro, A
Turner, ML
Maitlis, PM
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 674 (1-2) : 45 - 49
[30] Solution and Nujol matrix photochemistry of (η5-C5H5)2Os2(CO)4 and Nujol matrix photochemistry of (η5-C5H4CH3)2Ru2(CO)4 and (η5-C5H5)M(CO)2H, where M = Ru and Os
Bitterwolf, TE
Linehan, JC
Shade, JE
ORGANOMETALLICS, 2001, 20 (04) : 775 - 781

← 1 2 3 4 5 →