Synthesis and solid-state structure of [(η2:η5-C5Me4CH2CH2CH = CH2)Ru(η3-C3H5)]

被引：17

作者：

Castro, A ^{[1
]}

Turner, ML ^{[1
]}

Maitlis, PM ^{[1
]}

机构：

[1] Univ Sheffield, Dept Chem, Sheffield S3 7HF, S Yorkshire, England

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 674卷 / 1-2期

关键词：

ruthenium complexes; functionalized cyclopentadienyl ligand; olefin chelate; crystal structures;

D O I：

10.1016/S0022-328X(03)00207-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Treatment of the tetramethylfulvene-Ru(II) complex [(eta(6)-C5Me4CH2)RuCl2](2) with allylmagnesium chloride leads to the allyl ruthenium Complex [(eta(2):eta(5)-C5Me4CH2CH2CH=CH2)Ru(eta(3)-C3H5)], which has been characterized spectroscopically and by a single crystal X-ray determination. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：45 / 49

页数：5

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