ASPECTS OF THE CHEMISTRY OF THE MIXED FERROCENE [MEO(CH2CH2O)3(CH2)3C5ME4]FE(C5H5) - GENERATION OF THE UNUSUAL ALPHA-FERROCENYL CARBOCATION ([MEO(CH2CH2O)3(CH2)3C5ME4]FE(C5H4CH2))+

被引：9

作者：

SIEMELING, U

HUFFMANN, G

机构：

[1] Fakultät für Chemie der Universität Bielefeld, D-33615 Bielefeld

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1994年 / 475卷 / 1-2期

关键词：

IRON; FERROCENE;

D O I：

10.1016/0022-328X(94)84026-1

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The mixed ferrocene [MeO(CH2CH2O)3(CH2)3C5Me4]Fe(C5H5) (1), accessible by reaction of C5H5Li with [MeO(CH2CH2O)3(CH2)3C5Me4]FeCl, is formylated with POCl3/DMF (DMF = N,N-dimethylformamide) to give the ferrocenyl aldehyde [MeO(CH2CH2O)3(CH2)3C5Me4]Fe(C5H4CHO) (2). Compound 2 is reduced with LiAlH4 to yield the alcohol [MeO(CH2CH2O)3(CH2)3C5Me4]Fe(C5H4CH2OH) (3), which is an excellent precursor for the unusual a-ferrocenyl carbocation {[MeO(CH2CH2O)3(CH2)3C5Me4]Fe(C5H4CH2)}+ (A+).

引用

页码：229 / 232

页数：4

共 50 条

[1] [MEO(CH2CH2O)(3)(CH2)(3)C(5)ME(4)]FECL - A HALFSANDWICH IRON(II) CHLORIDE COMPLEX OF REMARKABLE STABILITY
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[J]. CHEMISCHE BERICHTE, 1995, 128 (11) : 1135 - 1136
[2] Synthesis and solid-state structure of [(η2:η5-C5Me4CH2CH2CH = CH2)Ru(η3-C3H5)]
Castro, A
Turner, ML
Maitlis, PM
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2003, 674 (1-2) : 45 - 49
[3] [(C5H5)FE(C(5)H(4)CH(2)NME(2))] AS A PROMOTER FOR THE SYNTHESIS OF THE 1,2-DISUBSTITUTED FERROCENYL ALDEHYDES [(C5H5)FE(1,2-C5H3(CHO)(CH(2)NME2)] AND [(C5H5)FE(1,2-C5H3(CHO)CH(2)NME(CH2)(2)OCH=CH2)]
DELAVAUX-NICOT, B
GUARI, Y
MATHIEU, R
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1995, 489 (1-2) : C87 - C89
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Tian, J
Li, H
Hu, NH
Huang, BT
[J]. ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1996, 52 : 19 - 21
[5] ABINITIO STUDY OF THE INTERACTION OF FE, FE+, AND HFE WITH H, CH, CH2, CH3, AND C5H5
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[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1990, 112 (07) : 2601 - 2607
[6] Syntheses and reactivity of functionalized (η5-tetramethylcyclopentadienyl) rhenium complexes:: Molecular structures of (η5:η2-C5Me4CH2CH2CH=CH2)Re(CO)2 and (η5-C5Me4CH2-2-C4H3S)Re(CO)2(PMe3)
Godoy, F
Klahn, AH
Lahoz, FJ
Balana, AI
Oelckers, B
Oro, LA
[J]. ORGANOMETALLICS, 2003, 22 (24) : 4861 - 4868
[7] Dissociative photoionization of CH3C(O)CH2 to C2H5+
Alligood, Bridget W.
Womack, Caroline C.
Rynteson, Matthew D.
Butler, Laurie J.
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[8] EXCESS MOLAR VOLUMES AT THE TEMPERATURE 298.15-K OF (X1C2H5CO2(CH2)2CH3+X2CL(CH2)5CH3+(1-X1-X2)C-C6H12), (X1C2H5CO2(CH2)2CH3+X2CL(CH2)5CH3+(1-X1-X2)CH3(CH2)4CH3), AND (X1C2H5CO2(CH2)2CH3+X2C-C6H12+(1-X1-X2)CH3(CH2)4CH3)
SOUZA, MJ
JIMENEZ, E
LEGIDO, JL
FERNANDEZ, J
MARTELL, EP
ANDRADE, MIP
[J]. JOURNAL OF CHEMICAL THERMODYNAMICS, 1992, 24 (02): : 119 - 128
[9] STRUCTURE OF PI-C5H5RH(CH2=CHF)2 AND PI-C5H5RH(CH2=CHF)(CH2=CH2)
CRAMER, R
REDDY, GS
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[10] SYNTHESIS, CHARACTERIZATION, AND REACTIONS OF (C5H5)(CO)2FE=C(CH3)2+ AND (C5H5)(CO)2FE=CH-CH=C(CH3)2+
CASEY, CP
MILES, WH
TUKADA, H
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1985, 107 (10) : 2924 - 2931

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