[(C5H5)FE(C(5)H(4)CH(2)NME(2))] AS A PROMOTER FOR THE SYNTHESIS OF THE 1,2-DISUBSTITUTED FERROCENYL ALDEHYDES [(C5H5)FE(1,2-C5H3(CHO)(CH(2)NME2)] AND [(C5H5)FE(1,2-C5H3(CHO)CH(2)NME(CH2)(2)OCH=CH2)]

被引：6

作者：

DELAVAUX-NICOT, B ^{[1
]}

GUARI, Y ^{[1
]}

MATHIEU, R ^{[1
]}

机构：

[1] INST NATL POLYTECH TOULOUSE, F-31077 TOULOUSE, FRANCE

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1995年 / 489卷 / 1-2期

关键词：

IRON; FERROCENYL ALDEHYDES; SYNTHESIS;

D O I：

10.1016/0022-328X(94)05326-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The one pot synthesis of [(C5H5)Fe(1,2-C5H3(CHO)(CH(2)NMe(2))}] (2) from [(C5H5)Fe(C(5)H(4)CH(2)NMe(2))] (1) is described. The new biferrocenyl compound [{(C5H5)FeC(5)H(4)CH(2)ONMe(CH2)(2)OCH2}(2)] (3), whose preparation is reported, reacts successively with 2 mole equivalents of LiBu and DMF (-78 degrees C) to give, among other products, the aldehyde [(C5H5)Fe(1,2-C5H3(CHO)CH(2)NMe(CH2)(2)OCH=CH2}] (6).

引用

页码：C87 / C89

页数：3

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