Synthetic, spectroscopic, and structural studies of bis(2-methyl-4phenylpentadienyl)ruthenium, Ru(2-CH3-4-C6H5C5H5)2:: characterization of isomeric open ruthenocenes

被引：5

作者：

Turpin, GC

Rheingold, AL ^{[1
]}

Ernst, RD

机构：

[1] Univ Delaware, Dept Chem, Newark, DE 19716 USA

[2] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 672卷 / 1-2期

关键词：

ruthenium complexes; diastereomers; structural studies; pentadienyl complexes;

D O I：

10.1016/S0022-328X(03)00149-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ru(2-methyl-4-phenylpentadienyl), has been isolated from the reaction of ruthenium chloride complexes with the appropriate diene and zinc metal in ethanol. The complex exists as a pair of diastereomers, which could be readily separated due to their significantly different solubilities. Structural studies reveal, as expected, that one of the isomers exists in the C-1 point group, while the other possesses (noncrystallographic) C-2 symmetry. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：109 / 114

页数：6

共 50 条

[11] CHEMICAL, STRUCTURAL AND SPECTROSCOPIC STUDIES OF [(ETA-5-CH3C5H4)2(CO)4MO2(C3H4)]BF4.
MAYER, A
CURTIS, MD
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1984, 187 (APR): : 183 - INOR
[12] Mono- and bis(cyclopalladation) of the bis(ferrocenylimine) [(eta(5)-C5H5)Fe{(eta(5)-C5H4)-CH=N-(C6H3-2-CH3)-}](2)
Lopez, C
Bosque, R
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1996, 524 (1-2) : 247 - 252
[13] SYNTHESIS AND CHARACTERIZATION OF [IR2(TMB)4H2][B(C6H5)4]2.CH3C6H5
SMITH, DC
MARSH, RE
SCHAEFER, WP
LOEHR, TM
GRAY, HB
INORGANIC CHEMISTRY, 1990, 29 (03) : 534 - 538
[14] Arene-ruthenium complexes with ferrocene-derived ligands: Synthesis and characterization of complexes of the type [Ru(η6-arene)(NC5H4CH2NHOC-C5H4FeC5H5)Cl2] and [Ru(η6-arene)(NC3H3N(CH2)2O2C-C5H4FeC5H5)Cl2]
Auzias, Mathieu
Gueniat, Joeel
Therrien, Bruno
Suess-Fink, Georg
Renfrew, Anna K.
Dyson, Paul J.
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 2009, 694 (06) : 855 - 861
[15] PREPARATION AND CHARACTERIZATION OF (C6H5CH2CH2NH3)2SNI4 AND (C6H5CH2CH2NH3)2SNBR4
PAPAVASSILIOU, GC
KOUTSELAS, JB
LAGOUVARDOS, DJ
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1993, 48 (07): : 1013 - 1014
[16] UHV surface chemistry of bis(ethylcyclopentadienyl)ruthenium, (C2H5C5H4)2Ru, on an oxide substrate
Luo, B
Wang, Q
White, JM
CHEMICAL VAPOR DEPOSITION, 2004, 10 (06) : 311 - 317
[17] Synthesis and photochemistry of ring-coupled heterobimetallic compounds of ruthenium.: The molecular structures of RuM(CO)5(μ-η5,η5-C5H4CR2C5H4), where M = Mo, R = CH3;: M = W, R = H, [Ru(CO)2][Mo(CO)3Cl](μ-η5,η1:η5-C5H4CH2C5H3) and [W(CO)3][Ru(CO)2Cl](μ-η5,η1:η5-C5H4CH2C5H3)
Bitterwolf, TE
Saygh, AA
Shade, JE
Rheingold, AL
Yap, GPA
Lable-Sands, LM
INORGANICA CHIMICA ACTA, 2000, 300 : 800 - 809
[18] FROM MONONUCLEAR (C5H5CH2C5H4)M TO UNSYMMETRICAL DINUCLEAR M(C5H4CH2C5H4)M AND HETERODINUCLEAR M(C5H4CH2C5H4)M' TRANSITION-METAL COMPLEXES
SCHNEIDER, D
WERNER, H
ORGANOMETALLICS, 1993, 12 (11) : 4420 - 4430
[19] Syntheses and crystal structures of [(C6H5CH2C5H4)(2)GdCl center dot THF](2) and (C6H5CH2C5H4)(2)ErCl center dot THF
Xia, JS
Jin, ZS
Chen, WQ
CHINESE JOURNAL OF CHEMISTRY, 1996, 14 (01) : 31 - 39
[20] THE GAS-PHASE SOLVATION OF C2H5+, S-C3H7+, AND S-C4H9+ WITH CH4 - THE ISOMERIC STRUCTURES OF C2H5+ AND C2H5+...CH4
HIRAOKA, K
MORI, T
YAMABE, S
CHEMICAL PHYSICS LETTERS, 1993, 207 (2-3) : 178 - 184

← 1 2 3 4 5 →