Synthetic, spectroscopic, and structural studies of bis(2-methyl-4phenylpentadienyl)ruthenium, Ru(2-CH3-4-C6H5C5H5)2:: characterization of isomeric open ruthenocenes

被引：5

作者：

Turpin, GC

Rheingold, AL ^{[1
]}

Ernst, RD

机构：

[1] Univ Delaware, Dept Chem, Newark, DE 19716 USA

[2] Univ Utah, Dept Chem, Salt Lake City, UT 84112 USA

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2003年 / 672卷 / 1-2期

关键词：

ruthenium complexes; diastereomers; structural studies; pentadienyl complexes;

D O I：

10.1016/S0022-328X(03)00149-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Ru(2-methyl-4-phenylpentadienyl), has been isolated from the reaction of ruthenium chloride complexes with the appropriate diene and zinc metal in ethanol. The complex exists as a pair of diastereomers, which could be readily separated due to their significantly different solubilities. Structural studies reveal, as expected, that one of the isomers exists in the C-1 point group, while the other possesses (noncrystallographic) C-2 symmetry. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：109 / 114

页数：6

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