Palladium-Catalyzed Hydroxymethylation of Aryl- and Heteroarylboronic Acids using Aqueous Formaldehyde

被引：19
|
作者：
Yamamoto, Tetsuya [1 ,2 ]
Zhumagazin, Azamat [1 ]
Furusawa, Takuma [1 ]
Tanaka, Ryoji [3 ]
Yamakawa, Tetsu [1 ]
Oe, Yohei [2 ]
Ohta, Tetsuo [2 ]
机构：
[1] Sagami Chem Res Inst, Catalysis Grp, Ayase, Kanagawa 2521193, Japan
[2] Doshisha Univ, Dept Biomed Informat, Fac Life & Med Sci, Kyoto 6100394, Japan
[3] Sagami Chem Res Inst, Instrumental Anal Grp, Ayase, Kanagawa 2521193, Japan
来源：
ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 17期
关键词：
1,2-addition; cyclometallated palladium complexes; formaldehyde; N-heterocyclic carbenes; palladium catalyst; N-HETEROCYCLIC CARBENES; ARYLBORONIC ACIDS; ADDITION-REACTIONS; CO SOURCE; ORTHOPLATINATED TRIARYLPHOSPHITE; CARBONYLATION REACTIONS; ASYMMETRIC-SYNTHESIS; CARBON-MONOXIDE; BORONIC ACIDS; ME-BIPAM;
D O I：
10.1002/adsc.201400845
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Cyclometallated NHC palladium complexes prepared from palladium(II) acetate [Pd(OAc)(2)] and unsymmetrical 1,3-diarylimidazolinium salts catalyzed the hydroxymethylation of (hetero)arylboronic acids using an excess amount of formalin to afford (hetero)arylmethanols in good to satisfactory yields.
引用
收藏
页码：3525 / 3529
页数：5
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