Palladium-Catalyzed Hydroxymethylation of Aryl- and Heteroarylboronic Acids using Aqueous Formaldehyde

被引：19

作者：

Yamamoto, Tetsuya ^{[1
,2
]}

Zhumagazin, Azamat ^{[1
]}

Furusawa, Takuma ^{[1
]}

Tanaka, Ryoji ^{[3
]}

Yamakawa, Tetsu ^{[1
]}

Oe, Yohei ^{[2
]}

Ohta, Tetsuo ^{[2
]}

机构：

[1] Sagami Chem Res Inst, Catalysis Grp, Ayase, Kanagawa 2521193, Japan

[2] Doshisha Univ, Dept Biomed Informat, Fac Life & Med Sci, Kyoto 6100394, Japan

[3] Sagami Chem Res Inst, Instrumental Anal Grp, Ayase, Kanagawa 2521193, Japan

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 17期

关键词：

1,2-addition; cyclometallated palladium complexes; formaldehyde; N-heterocyclic carbenes; palladium catalyst; N-HETEROCYCLIC CARBENES; ARYLBORONIC ACIDS; ADDITION-REACTIONS; CO SOURCE; ORTHOPLATINATED TRIARYLPHOSPHITE; CARBONYLATION REACTIONS; ASYMMETRIC-SYNTHESIS; CARBON-MONOXIDE; BORONIC ACIDS; ME-BIPAM;

D O I：

10.1002/adsc.201400845

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Cyclometallated NHC palladium complexes prepared from palladium(II) acetate [Pd(OAc)(2)] and unsymmetrical 1,3-diarylimidazolinium salts catalyzed the hydroxymethylation of (hetero)arylboronic acids using an excess amount of formalin to afford (hetero)arylmethanols in good to satisfactory yields.

引用

页码：3525 / 3529

页数：5

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