Palladium-catalyzed direct arylation of (hetero)arenes with aryl boronic acids

被引：396
|
作者：
Yang, Shang-Dong [1 ]
Sun, Chang-Liang [1 ]
Fang, Zhao [1 ]
Li, Bi-He [1 ]
Li, Yi-Zhou [1 ]
Shi, Zhang-Jie [1 ,2 ]
机构：
[1] Peking Univ, Coll Chem, PKU Green Chem Ctr, BNLMS,Key Lab Bioorgan Chem & Mol Engn, Beijing 100871, Peoples R China
[2] Chinese Acad Sci, State Key Lab Organ Chem, Shanghai 200032, Peoples R China
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 08期
关键词：
arenes; C-C coupling; C-H activation; homogeneous catalysis; palladium;
D O I：
10.1002/anie.200704619
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) No compass required: A method is described for forming biaryl C-C bonds by a PdII-catalyzed cross-coupling of aryl C-H bonds with aryl boronic acids under mild conditions without the presence of directing groups. Different substituents on both (hetero)arenes and aryl boronic acids are compatible with the reaction conditions, and the homocoupling of boronic acids is highly inhibited. Dioxygen was applied as the final oxidant. © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.
引用
收藏
页码：1473 / 1476
页数：4
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