Synthesis of Aryl Sulfonamides via Palladium-Catalyzed Chlorosulfonylation of Arylboronic Acids

被引：91
|
作者：
DeBergh, J. Robb [1 ]
Niljianskul, Nootaree [1 ]
Buchwald, Stephen L. [1 ]
机构：
[1] MIT, Dept Chem, Cambridge, MA 02139 USA
来源：
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2013年 / 135卷 / 29期
基金：
美国国家卫生研究院;
关键词：
MIYAURA COUPLING REACTIONS; CHLORINE BOND SCISSION; ONE-POT SYNTHESIS; CROSS-COUPLINGS; SULFONYL CHLORIDES; HETEROARYL SULFONAMIDES; SULFUR-COMPOUNDS; METHANOLYSIS; DISCOVERY; THIOLS;
D O I：
10.1021/ja405949a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A palladium-catalyzed method for the preparation of sulfonamides is described. The process exhibits significant functional group tolerance and allows for the preparation of a number of arylsulfonyl chlorides and sulfonamides under mild conditions.
引用
收藏
页码：10638 / 10641
页数：4
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