Transition-Metal-Free Three-Component Reaction: Additive Controlled Synthesis of Sulfonylated Imidazoles

被引：21

作者：

Liu, Wei ^{[1
]}

Zhang, Yu ^{[1
]}

He, Jiaming ^{[1
]}

Yu, Yue ^{[1
]}

Yuan, Jiajun ^{[1
]}

Ye, Xiaoyi ^{[1
]}

Zhang, Ziwu ^{[1
]}

Xue, Liang ^{[1
]}

Cao, Hua ^{[1
]}

机构：

[1] Guangdong Pharmaceut Univ, Sch Chem & Chem Engn, Zhongshan 528458, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2019年 / 84卷 / 17期

基金：

中国国家自然科学基金;

关键词：

ONE-POT SYNTHESIS; C-S BOND; SULFONES; OXIDATION; ACCESS; ARYL; STRATEGY; HALIDES; ALKYNES; VINYL;

D O I：

10.1021/acs.joc.9b01818

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Two efficient transition-metal-free highly regioselective pathways for constructing sulfonylated imidazoles via three-component reactions of amidines, ynals, and sodium sulfonates have been developed. The generations of different sulfonylated imidazoles were simply controlled by additives. In addition, this method features environmental friendliness, good functional group tolerance, and high atom economy, which makes it practical.

引用

页码：11348 / 11358

页数：11

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