Synthesis and structure of the pentanuclear mixed-metal cluster [Co4MoCp(μ3-SBut) (μ3-S) (μ3-CO) (μ-CO)2(CO)6]

被引：1

作者：

King, JD

Mays, MJ

McPartlin, M

Radojevic, S

Sarveswaran, V

Solan, GA

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ N London, Sch Appl Chem, London N7 8DB, England

[3] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 04期

关键词：

crystal structures; mixed-metal complexes; cobalt complexes; molybdenum complexes; sulfur complexes; cluster complexes;

D O I：

10.1016/S1387-7003(00)00030-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pentanuclear mixed-metal cluster [Co4MoCp(mu(3)-SBut) (mu(3)-S)(mu(3)-CO)(mu-CO)(2)(CO)(6)] (1) has been synthesised by reaction of [CoMoCp(CO)(7)] with (BuSSBut)-S-t. X-ray structural analysis identified an asymmetric unit with three cobalt atoms and one molybdenum forming an irregular tetrahedron while one cobalt-molybdenum edge is bridged by a cobalt atom. Crystal data: space group P2(1)/n, a = 10.162(2), b = 13.722(3), c= 17.69(5) Angstrom, beta = 91.44(2)degrees, Z=4. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：159 / 162

页数：4

共 50 条

[31] CRYSTAL STRUCTURE OF MIXED-METAL CLUSTER （η5-C5H5）2W2Fe2（μ3-S）2（CO）8
Zheng Bi-Xian Huang Jin-Shun Lu Jia-XiFuzhou laboratory of Structural Chemistry
[J]. Chinese Journal of Structural Chemistry, 1991, (03) : 231 - 233
[32] Synthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(μ5-C)(μ3-CO)(CO)13Cp*]
Lau, JPK
Wong, WT
[J]. INORGANIC CHEMISTRY COMMUNICATIONS, 2003, 6 (06) : 733 - 736
[33] Synthesis and characterization of (Cp*Ru)3Co(CO)2(μ3-CO)B3H3 (Cp* = η5-C5Me5):: A metallaborane with cubane cluster structure
Lei, XJ
Shang, MY
Fehlner, TP
[J]. ORGANOMETALLICS, 2000, 19 (22) : 4429 - 4431
[34] Synthesis and structural characterisation of the mixed metal clusters [Rh2Pt3(μ-CO)5(CO)4(PPh3)3] and [Rh2Pt2(μ-CO)3-(CO)4(PPh3)3];: crystal structure of [Rh2Pt3(μ-CO)5(CO)4(PPh3)3]
Dolgushin, FM
Grachova, EV
Heaton, BT
Iggo, JA
Koshevoy, IO
Podkorytov, IS
Smawfield, DJ
Tunik, SP
Whyman, R
Yanovskii, AI
[J]. JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1999, (10): : 1609 - 1614
[35] CRYSTAL STRUCTURE OF A NOVEL TETRANUCLEAR MIXED-METAL CLUSTER Mo2Fe2Te3（CO）6（C3H3）2
Yang Xiaoguang Huang Jinshun Huang JinlingFujian Institute of Research on the Structure of Matter
[J]. Chinese Journal of Structural Chemistry, 1985, (02) : 90 - 92
[36] PHOTOASSISTED SYNTHESIS OF MIXED-METAL CLUSTERS - [PPN][COOS3(CO)13], H2RUOS3(CO)13, AND H2FEOS3(CO)13
BURKHARDT, EW
GEOFFROY, GL
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 198 (02) : 179 - 188
[37] Mixed-metal cluster chemistry IX:: alkylarylphosphine derivatives of [CpWIr3(CO)11] and X-ray crystal structure of [CpWIr3(μ-CO)3(CO)7(PMe2Ph)]2
Waterman, SM
Humphrey, MG
Hockless, DCR
[J]. JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1998, 565 (1-2) : 81 - 95
[38] AN UNUSUAL MIXED-METAL CLUSTER - SYNTHESIS AND MOLECULAR-STRUCTURE OF FEPT5(CO)9(PET3)4
BENDER, R
BRAUNSTEIN, P
BAYEUL, D
DUSAUSOY, Y
[J]. INORGANIC CHEMISTRY, 1989, 28 (12) : 2381 - 2384
[39] 簇合物Co4(μ3-S)〔P(S)(OCH3)2〕2(CO)9、Co4(μ,η~2-S2)〔P(O-i-C3H7)2〕2(CO)10和Co6(μ3-S)2(μ-“非汉字符”)(μ6,η~3-“非汉字符”)(μ-CO)(CO)10的合成和谱学表征
朱保华
刘树堂
吴秉芳
胡襄
[J]. 内蒙古大学学报(自然科学版), 2001, (04) : 415 - 418
[40] The structure of [Co3(η5-C5H5)3(μ3-S)(μ3-CSMe)]+, and the reactions of the metal cluster cations [{Co(η5-C5H5)}2{Fe(CO)2(PPh3)}-(μ3-S)μ3-CSR)]+ and [{Co(η5-C5H5)}3(μ3-S)(μ3-CSR)]+ (R = Me, Et) with nucleophiles
Cromhout, NL
Manning, AR
Palmer, AJ
McAdam, CJ
Robinson, BH
Simpson, J
[J]. INORGANICA CHIMICA ACTA, 2003, 354 : 54 - 60

← 1 2 3 4 5 →