Synthesis, characterization, molecular and crystal structure of osmium-rhodium mixed-metal carbide cluster, [Os5Rh(μ5-C)(μ3-CO)(CO)13Cp*]

被引：5

作者：

Lau, JPK ^{[1
]}

Wong, WT ^{[1
]}

机构：

[1] Univ Hong Kong, Dept Chem, Hong Kong, Hong Kong, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2003年 / 6卷 / 06期

关键词：

osmium; rhodium; carbide; X-ray crystallography;

D O I：

10.1016/S1387-7003(03)00095-9

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The hexanuclear osmium-rhodium carbonyl carbide cluster [OsRh(mu(5)-C)(mu(3)-CO)(CO)(13)Cp*] 3 has been synthesized in 66% yield by the ionic coupling reaction of [N(PPh3)(2)](2)[Os5C(CO)(14)] 1 with [Rh-2(Cp*)(2)][BF4](2) 2. An X-ray analysis on 3 showed a square based pyramidal metal skeleton with a mu(3)-CO bridging a RhOs2 triangular face. (C) 2003 Elsevier Science B.V. All rights reserved.

引用

页码：733 / 736

页数：4

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