Synthesis and structure of the pentanuclear mixed-metal cluster [Co4MoCp(μ3-SBut) (μ3-S) (μ3-CO) (μ-CO)2(CO)6]

被引：1
|
作者：
King, JD
Mays, MJ
McPartlin, M
Radojevic, S
Sarveswaran, V
Solan, GA
机构：
[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England
[2] Univ N London, Sch Appl Chem, London N7 8DB, England
[3] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 04期
关键词：
crystal structures; mixed-metal complexes; cobalt complexes; molybdenum complexes; sulfur complexes; cluster complexes;
D O I：
10.1016/S1387-7003(00)00030-7
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The pentanuclear mixed-metal cluster [Co4MoCp(mu(3)-SBut) (mu(3)-S)(mu(3)-CO)(mu-CO)(2)(CO)(6)] (1) has been synthesised by reaction of [CoMoCp(CO)(7)] with (BuSSBut)-S-t. X-ray structural analysis identified an asymmetric unit with three cobalt atoms and one molybdenum forming an irregular tetrahedron while one cobalt-molybdenum edge is bridged by a cobalt atom. Crystal data: space group P2(1)/n, a = 10.162(2), b = 13.722(3), c= 17.69(5) Angstrom, beta = 91.44(2)degrees, Z=4. (C) 2000 Elsevier Science S.A. All rights reserved.
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页码：159 / 162
页数：4
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