Synthesis and structure of the pentanuclear mixed-metal cluster [Co4MoCp(μ3-SBut) (μ3-S) (μ3-CO) (μ-CO)2(CO)6]

被引：1

作者：

King, JD

Mays, MJ

McPartlin, M

Radojevic, S

Sarveswaran, V

Solan, GA

机构：

[1] Univ Cambridge, Dept Chem, Cambridge CB2 1EW, England

[2] Univ N London, Sch Appl Chem, London N7 8DB, England

[3] Univ Leicester, Dept Chem, Leicester LE1 7RH, Leics, England

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2000年 / 3卷 / 04期

关键词：

crystal structures; mixed-metal complexes; cobalt complexes; molybdenum complexes; sulfur complexes; cluster complexes;

D O I：

10.1016/S1387-7003(00)00030-7

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The pentanuclear mixed-metal cluster [Co4MoCp(mu(3)-SBut) (mu(3)-S)(mu(3)-CO)(mu-CO)(2)(CO)(6)] (1) has been synthesised by reaction of [CoMoCp(CO)(7)] with (BuSSBut)-S-t. X-ray structural analysis identified an asymmetric unit with three cobalt atoms and one molybdenum forming an irregular tetrahedron while one cobalt-molybdenum edge is bridged by a cobalt atom. Crystal data: space group P2(1)/n, a = 10.162(2), b = 13.722(3), c= 17.69(5) Angstrom, beta = 91.44(2)degrees, Z=4. (C) 2000 Elsevier Science S.A. All rights reserved.

引用

页码：159 / 162

页数：4

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