CRYSTAL STRUCTURE OF A NOVEL TETRANUCLEAR MIXED-METAL CLUSTER Mo2Fe2Te3（CO）6（C3H3）2

被引：0

作者：

Yang Xiaoguang Huang Jinshun Huang JinlingFujian Institute of Research on the Structure of Matter

机构：

来源：

Chinese Journal of Structural Chemistry | 1985年 / 02期

关键词：

Mo; Te; Ho; C3H3; Fe; CRYSTAL STRUCTURE OF A NOVEL TETRANUCLEAR MIXED-METAL CLUSTER Mo2Fe2Te3; CO;

D O I：

10.14102/j.cnki.0254-5861.1985.02.004

中图分类号：

学科分类号：

摘要：

Mr = 984. 63, orthorhombic Imm2, a = 14.562(3), b = 10.391(1), c = 7.139(4) A; V = 1080.2(1) A3, Z = 2, DC = 3.027 g.cm-3. Final R= 0.022 for 620 reflections with I > 20(Ⅰ). In the title compound, four metal atoms form a butterfly configuration, one ,μ-Te is bonded to these four metals and two μ3-Te cap two Fe-Mo-Mo faces. All these atoms as a whole give a bicapped trigonal bipyramidal structure.

引用

页码：90 / 92

页数：3

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