Effect of pressure on the rate of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene

被引：6
|
作者：
Kiselev, V. D. [1 ]
Kornilov, D. A. [1 ]
Kashaeva, E. A. [1 ]
Potapova, L. N. [1 ]
Konovalov, A. I. [2 ]
机构：
[1] Kazan Volga Reg Fed Univ, Butlerov Inst Chem, Kazan 420008, Tatarstan, Russia
[2] Russian Acad Sci, Arbuzov Inst Organ & Phys Chem, Kazan Sci Ctr, Kazan 420088, Tatarstan, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 50卷 / 04期
关键词：
Maleic Anhydride; Fumaric Acid; Cyclopentadiene; Alder Reaction; Dimethyl Fumarate;
D O I：
10.1134/S1070428014040071
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The enthalpy, entropy, and volume of activation and volume of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene in 1,2-dichloroethane have been determined. Possible factors responsible for the sharp difference between the volumes of activation and reaction are considered.
引用
收藏
页码：489 / 493
页数：5
相关论文
共 50 条
  • [41] ORGANIC REACTION UNDER HIGH-PRESSURE .12. EFFECT OF PRESSURE ON DIELS-ALDER REACTION
    SEGUCHI, K
    SERA, A
    MARUYAMA, K
    BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN, 1974, 47 (09) : 2242 - 2246
  • [42] REGIOSELECTIVITY IN THE DIELS-ALDER REACTION OF 9-SUBSTITUTED ANTHRACENES
    ALSTON, PV
    OTTENBRITE, RM
    NEWBY, J
    JOURNAL OF ORGANIC CHEMISTRY, 1979, 44 (26): : 4939 - 4943
  • [43] CORRELATIONS OF RATE AND SELECTIVITY OF A DIELS-ALDER REACTION WITH SP PARAMETERS
    CATIVIELA, C
    MAYORAL, JA
    AVENOZA, A
    PEREGRINA, JM
    ROY, MA
    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1990, 3 (06) : 414 - 418
  • [44] Diffusion control of the Diels-Alder reaction rate at elevated pressures
    Kiselev, VD
    Kashaeva, EA
    Shihab, MS
    Potapova, LN
    Iskhakova, GG
    RUSSIAN CHEMICAL BULLETIN, 2004, 53 (01) : 45 - 50
  • [45] RATE ENHANCEMENT IN ETHANOLIC AQUEOUS BUFFER - THE DIELS-ALDER REACTION
    SMITH, MB
    FAY, JN
    SON, YC
    CHEMISTRY LETTERS, 1992, (12) : 2451 - 2454
  • [46] Effect of solvent motions on the dynamics of the Diels-Alder reaction
    Zhang, Xiaoyong
    Lefebvre, Pierre-Louis
    Harvey, Jeremy N.
    PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2022, 24 (02) : 1120 - 1130
  • [47] A THEORETICAL EVALUATION OF THE CAPTODATIVE EFFECT IN THE DIELS-ALDER REACTION
    MOYANO, A
    OLIVELLA, S
    JOURNAL OF MOLECULAR STRUCTURE-THEOCHEM, 1990, 67 (3-4): : 261 - 269
  • [48] AN UNUSUAL SOLVENT EFFECT IN AN INTRAMOLECULAR DIELS-ALDER REACTION
    HANDA, S
    JONES, K
    NEWTON, CG
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1986, (24) : 1797 - 1799
  • [49] SUBSTITUENT EFFECT IN DIELS-ALDER REACTION-MECHANISM
    OLIVA, A
    BERTRAN, J
    FERNANDEZALONSO, JI
    BULLETIN DES SOCIETES CHIMIQUES BELGES, 1976, 85 (12): : 1021 - 1022
  • [50] SECONDARY DEUTERIUM ISOTOPE EFFECT ON DIELS-ALDER REACTION
    VANSICKLE, DE
    RODIN, JO
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1964, 86 (15) : 3091 - &
12345