Effect of pressure on the rate of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene

被引：6

作者：

Kiselev, V. D. ^{[1
]}

Kornilov, D. A. ^{[1
]}

Kashaeva, E. A. ^{[1
]}

Potapova, L. N. ^{[1
]}

Konovalov, A. I. ^{[2
]}

机构：

[1] Kazan Volga Reg Fed Univ, Butlerov Inst Chem, Kazan 420008, Tatarstan, Russia

[2] Russian Acad Sci, Arbuzov Inst Organ & Phys Chem, Kazan Sci Ctr, Kazan 420088, Tatarstan, Russia

来源：

RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 50卷 / 04期

关键词：

Maleic Anhydride; Fumaric Acid; Cyclopentadiene; Alder Reaction; Dimethyl Fumarate;

D O I：

10.1134/S1070428014040071

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The enthalpy, entropy, and volume of activation and volume of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene in 1,2-dichloroethane have been determined. Possible factors responsible for the sharp difference between the volumes of activation and reaction are considered.

引用

页码：489 / 493

页数：5

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