Effect of pressure on the rate of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene

被引：6
|
作者：
Kiselev, V. D. [1 ]
Kornilov, D. A. [1 ]
Kashaeva, E. A. [1 ]
Potapova, L. N. [1 ]
Konovalov, A. I. [2 ]
机构：
[1] Kazan Volga Reg Fed Univ, Butlerov Inst Chem, Kazan 420008, Tatarstan, Russia
[2] Russian Acad Sci, Arbuzov Inst Organ & Phys Chem, Kazan Sci Ctr, Kazan 420088, Tatarstan, Russia
来源：
RUSSIAN JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 50卷 / 04期
关键词：
Maleic Anhydride; Fumaric Acid; Cyclopentadiene; Alder Reaction; Dimethyl Fumarate;
D O I：
10.1134/S1070428014040071
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The enthalpy, entropy, and volume of activation and volume of the Diels-Alder reaction of diethyl azodicarboxylate with 9,10-dimethylanthracene in 1,2-dichloroethane have been determined. Possible factors responsible for the sharp difference between the volumes of activation and reaction are considered.
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页码：489 / 493
页数：5
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