RATE ENHANCEMENT IN ETHANOLIC AQUEOUS BUFFER - THE DIELS-ALDER REACTION

被引：3
|
作者：
SMITH, MB
FAY, JN
SON, YC
机构：
来源：
CHEMISTRY LETTERS | 1992年 / 12期
关键词：
D O I：
10.1246/cl.1992.2451
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We have observed a 2.5-3-fold increase in the rate of Diels-Alder reactions when done in aqueous ethanol, where the aqueous solution was prepared with a pH 7 buffer. This is a simple, inexpensive and convenient method for modest acceleration of the Diels-Alder reaction, in addition to the rate increase normally observed in aqueous media.
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页码：2451 / 2454
页数：4
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