RATE ENHANCEMENT IN ETHANOLIC AQUEOUS BUFFER - THE DIELS-ALDER REACTION

被引：3
|
作者：
SMITH, MB
FAY, JN
SON, YC
机构：
来源：
CHEMISTRY LETTERS | 1992年 / 12期
关键词：
D O I：
10.1246/cl.1992.2451
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
We have observed a 2.5-3-fold increase in the rate of Diels-Alder reactions when done in aqueous ethanol, where the aqueous solution was prepared with a pH 7 buffer. This is a simple, inexpensive and convenient method for modest acceleration of the Diels-Alder reaction, in addition to the rate increase normally observed in aqueous media.
引用
收藏
页码：2451 / 2454
页数：4
相关论文
共 50 条
  • [41] Spectacular Rate Enhancement of the Diels-Alder Reaction at the Ionic Liquid/n-Hexane Interface
    Beniwal, Vijay
    Manna, Arpan
    Kumar, Anil
    CHEMPHYSCHEM, 2016, 17 (13) : 1969 - 1972
  • [42] CORRELATIONS OF RATE AND SELECTIVITY OF A DIELS-ALDER REACTION WITH SP PARAMETERS
    CATIVIELA, C
    MAYORAL, JA
    AVENOZA, A
    PEREGRINA, JM
    ROY, MA
    JOURNAL OF PHYSICAL ORGANIC CHEMISTRY, 1990, 3 (06) : 414 - 418
  • [43] DIENE SUBSTITUENT EFFECT ON THE RATE OF THE RETRO DIELS-ALDER REACTION
    CHUNG, Y
    DUERR, B
    NANJAPPAN, P
    CZARNIK, AW
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1987, 193 : 150 - ORGN
  • [44] Diffusion control of the Diels-Alder reaction rate at elevated pressures
    Kiselev, VD
    Kashaeva, EA
    Shihab, MS
    Potapova, LN
    Iskhakova, GG
    RUSSIAN CHEMICAL BULLETIN, 2004, 53 (01) : 45 - 50
  • [45] Diels-Alder reactions in ionic media: Rate enhancement with green chemistry
    Kumar, A
    Deshpande, SS
    Pawar, SS
    NATIONAL ACADEMY SCIENCE LETTERS-INDIA, 2003, 26 (9-10): : 232 - 250
  • [46] Origin of rate enhancement and asynchronicity in iminium catalyzed Diels-Alder reactions
    Vermeeren, Pascal
    Hamlin, Trevor A.
    Fernandez, Israel
    Bickelhaupt, F. Matthias
    CHEMICAL SCIENCE, 2020, 11 (31) : 8105 - 8112
  • [47] ISOMERISM IN THE DIELS-ALDER REACTION .3. THE BROMINATION OF THE DIELS-ALDER ADDUCT, NORBORNYLENE
    KWART, H
    KAPLAN, L
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1954, 76 (16) : 4072 - 4077
  • [48] Study on Diels-Alder reaction of nitrosoalkenes
    Tang, Xiaoxiao
    Lu, Baozhao
    Chen, Yu
    Wang, Jiexue
    Jin, Liming
    Yang, Hongjun
    CHEMISTRY OF HETEROCYCLIC COMPOUNDS, 2023, 59 (11-12) : 811 - 815
  • [49] OCTACHLOROFULVALENE AS A DIENE IN THE DIELS-ALDER REACTION
    FRAY, GI
    JONES, CB
    PETTS, JC
    JOURNAL OF CHEMICAL RESEARCH-S, 1990, (08): : 260 - 261
  • [50] REVERSE DIELS-ALDER OR RETRODIENE REACTION
    KWART, H
    KING, K
    CHEMICAL REVIEWS, 1968, 68 (04) : 415 - +
12345