Synthesis and reactions of highly sterically hindered organosilicon compounds of the type (Me3Si)3CSi(C6H4-OMe-p)MeX and (Me3Si)3CSi(C6H4-Me-p)MeX

被引：3

作者：

Safa, KD ^{[1
]}

Bolourtchian, M ^{[1
]}

Asadi, MG ^{[1
]}

机构：

[1] Univ Tabriz, Fac Chem, Tabriz, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1999年 / 149卷

关键词：

anisole; electrophiles; nucleophiles; organosilicon; sterically hindered; tolyl; trisyl;

D O I：

10.1080/10426509908037034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Direct nucleophilic displacement of TsiSi(C6H4-OMe-p)MeI and TsiSi(C6H4-Me-p)MeI with nucleophiles take place. These compounds also react with electrophiles such as AgOAc and AgNO3 to give rearrangment products, for example (Me3Si)(2)C(SiMe(2)OAC)SiMe2 (C6H4-Y-p) (Y = Me, OMe). The hydrides and bromides of these compounds were also synthesised.

引用

页码：229 / 236

页数：8

共 50 条

[41] SYNTHESIS AND STRUCTURE OF THE NB-IV METALLOCYCLES [M(ETA-C5H4SIME3)2[CH2C6H4CH2-O]] (M=NB, R=ME3SI) AND REDUCTIVE CLEAVAGE OF D0 ANALOGS (M=TI, ZR, OR HF, R=H OR ME3SI) BY NA[C10H8]
LAPPERT, MF
MARTIN, TR
MILNE, CRC
ATWOOD, JL
HUNTER, WE
PENTILLA, RE
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1980, 192 (02) : C35 - C38
[42] Syntheses and crystal structures of [p-Me3NC6H4HgOC(O)Me][MeOSO3] and [(p-Me3NC6H4)2Hg][HgI]4]
Kuhn, Norbert
Abu-Salem, Qutaiba
Maichle-Moessmer, Caecilia
Steimann, Manfred
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2007, 633 (5-6): : 683 - 686
[43] Synthesis and characterization of zinc and cadmium compounds with arenephosphinothiol ligands.: Crystal and molecular structures of [Cd2{2-(Ph2PO)C6H4S}4], [Zn{2-(Ph2P)-6-(Me3Si)C6H3S)}2], [Cd{2-{Ph2PO)-6-(Me3Si)C6H3S}2(CH3OH)], and [Zn{PhPO(C6H4S-2)2}(bipy)]
Pérez-Lourido, P
Romero, J
García-Vázquez, JA
Sousa, A
Maresca, KP
Zubieta, J
INORGANIC CHEMISTRY, 1999, 38 (16) : 3709 - 3715
[44] NOVEL TRIS(TRIMETHYLSILYL)METHYLBORON COMPOUNDS - CRYSTAL-STRUCTURES OF THE DIBORANE ((ME3SI)3C) HB (MU-H)2BH(C(SIME3)3) AND THE BIS(AMINOBORYL)AMINE ((ME3SI)3C(NH2)B)2NH
ALJUAID, SS
EABORN, C
HITCHCOCK, PB
KUNDU, KK
MOLLA, ME
SMITH, JD
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 385 (01) : 13 - 21
[45] X-ray crystal structures of Cp*Ni(PEt3)X [X=Br, O(p-C6H4Me), NH(p-C6H4Me), S(p-C6H4Me), OCH3, CH2C6H5, Me, H, PEt3+].: Understanding distortions and transinfluences in cyclopentadienyl complexes
Holland, PL
Smith, ME
Andersen, RA
Bergman, RG
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1997, 119 (52) : 12815 - 12823
[46] STRUCTURAL STUDIES ON CYCLOPENTADIENYL COMPOUNDS OF TRIVALENT CERIUM - TETRAMERIC (MEC5H4)3CE AND MONOMERIC (ME3SIC5H4)3CE AND [(ME3SI)2C5H3]3CE AND THEIR COORDINATION CHEMISTRY
STULTS, SD
ANDERSEN, RA
ZALKIN, A
ORGANOMETALLICS, 1990, 9 (01) : 115 - 122
[47] Base-promoted hydroalkylation reactions of 1,3,5-Me3C6H3, C6Me, and p-MeC6H4CHMe2 ligands coordinated to ruthenium(II).
Nelson, JH
Ghebreyessus, K
ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2000, 219 : U794 - U794
[48] THE PREPARATION AND MOLECULAR-STRUCTURE OF THE HIGHLY STERICALLY HINDERED TRIS(TRIMETHYLSILYL)METHYLBORON COMPOUND (ME3SI)3CB(PH)[O(CH2)4C(SIME3)3]
EABORN, C
RETTA, N
SMITH, JD
HITCHCOCK, PB
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1982, 235 (03) : 265 - 271
[49] Synthesis and reactions of sterically encumbered, heteroleptic lanthanum phosphides. structural characterization of [{(Me3Si)2CH}-(C6H4-2-CH2NMe2)P]2La(OR) and [{(Me3Si)2CH}-(C6H4-2-CH2NMe2)P]La(THF)[P(C6H4-2-CH2NMe2)-{CH(SiMe3)(SiMe2CH2)}] [R= i-Pr, t-Bu]
Izod, K
Liddle, ST
McFarlane, W
Clegg, W
ORGANOMETALLICS, 2004, 23 (11) : 2734 - 2743
[50] Synthesis and X-ray Crystal Structures of Ru3(CO)9(μ-arphos)(L) [L = AsPh3, As(m-C6H4Me)3, As(p-C6H4Me)3]
Sirat, Siti Syaida
Bin Shawkataly, Omar
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 2019, 645 (09): : 683 - 687

← 1 2 3 4 5 →