NOVEL TRIS(TRIMETHYLSILYL)METHYLBORON COMPOUNDS - CRYSTAL-STRUCTURES OF THE DIBORANE ((ME3SI)3C) HB (MU-H)2BH(C(SIME3)3) AND THE BIS(AMINOBORYL)AMINE ((ME3SI)3C(NH2)B)2NH

被引：15
|
作者：
ALJUAID, SS
EABORN, C
HITCHCOCK, PB
KUNDU, KK
MOLLA, ME
SMITH, JD
机构：
[1] School of Chemistry and Molecular Sciences, University of Sussex, Brighton
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 385卷 / 01期
关键词：
D O I：
10.1016/0022-328X(90)87142-Z
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The dichloroborane RBCl2 (R = (Me3Si)3C) is reduced by LiBH4 to the diborane trans-RHB(μ-H)2BHR, which melts sharply at 183-185°C. It also reacts with ammonia to give the diaminoborane RB(NH2)2 which on warming in vacuum gives the bis(aminoboryl)amine {R(NH2)B}2NH. The structures of the diborane and the bis(aminoboryl)amine have been confirmed by X-ray diffraction. © 1990.
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页码：13 / 21
页数：9
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