NOVEL TRIS(TRIMETHYLSILYL)METHYLBORON COMPOUNDS - CRYSTAL-STRUCTURES OF THE DIBORANE ((ME3SI)3C) HB (MU-H)2BH(C(SIME3)3) AND THE BIS(AMINOBORYL)AMINE ((ME3SI)3C(NH2)B)2NH

被引：15

作者：

ALJUAID, SS

EABORN, C

HITCHCOCK, PB

KUNDU, KK

MOLLA, ME

SMITH, JD

机构：

[1] School of Chemistry and Molecular Sciences, University of Sussex, Brighton

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1990年 / 385卷 / 01期

关键词：

D O I：

10.1016/0022-328X(90)87142-Z

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The dichloroborane RBCl2 (R = (Me3Si)3C) is reduced by LiBH4 to the diborane trans-RHB(μ-H)2BHR, which melts sharply at 183-185°C. It also reacts with ammonia to give the diaminoborane RB(NH2)2 which on warming in vacuum gives the bis(aminoboryl)amine {R(NH2)B}2NH. The structures of the diborane and the bis(aminoboryl)amine have been confirmed by X-ray diffraction. © 1990.

引用

页码：13 / 21

页数：9

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