Synthesis and reactions of highly sterically hindered organosilicon compounds of the type (Me3Si)3CSi(C6H4-OMe-p)MeX and (Me3Si)3CSi(C6H4-Me-p)MeX

被引：3

作者：

Safa, KD ^{[1
]}

Bolourtchian, M ^{[1
]}

Asadi, MG ^{[1
]}

机构：

[1] Univ Tabriz, Fac Chem, Tabriz, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1999年 / 149卷

关键词：

anisole; electrophiles; nucleophiles; organosilicon; sterically hindered; tolyl; trisyl;

D O I：

10.1080/10426509908037034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Direct nucleophilic displacement of TsiSi(C6H4-OMe-p)MeI and TsiSi(C6H4-Me-p)MeI with nucleophiles take place. These compounds also react with electrophiles such as AgOAc and AgNO3 to give rearrangment products, for example (Me3Si)(2)C(SiMe(2)OAC)SiMe2 (C6H4-Y-p) (Y = Me, OMe). The hydrides and bromides of these compounds were also synthesised.

引用

页码：229 / 236

页数：8

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