Synthesis and reactions of highly sterically hindered organosilicon compounds of the type (Me3Si)3CSi(C6H4-OMe-p)MeX and (Me3Si)3CSi(C6H4-Me-p)MeX

被引：3

作者：

Safa, KD ^{[1
]}

Bolourtchian, M ^{[1
]}

Asadi, MG ^{[1
]}

机构：

[1] Univ Tabriz, Fac Chem, Tabriz, Iran

来源：

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 1999年 / 149卷

关键词：

anisole; electrophiles; nucleophiles; organosilicon; sterically hindered; tolyl; trisyl;

D O I：

10.1080/10426509908037034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Direct nucleophilic displacement of TsiSi(C6H4-OMe-p)MeI and TsiSi(C6H4-Me-p)MeI with nucleophiles take place. These compounds also react with electrophiles such as AgOAc and AgNO3 to give rearrangment products, for example (Me3Si)(2)C(SiMe(2)OAC)SiMe2 (C6H4-Y-p) (Y = Me, OMe). The hydrides and bromides of these compounds were also synthesised.

引用

页码：229 / 236

页数：8

共 50 条

[31] SYNTHESES AND CRYSTAL-STRUCTURES OF 2 BULKY AMINOHALOGENOSTANNANES, [(ME3SI)2CH]2SN(CL)N(H)(C6H2-2,4,6-TERT-BU3) AND [(ME3SI)2CH]2SN(F)N(H)(C6H2-2,4,6-TERT-BU3)
RAHARINIRINA, A
BOESE, R
SCHMID, G
JOURNAL OF ORGANOMETALLIC CHEMISTRY, 1990, 395 (01) : 39 - 45
[32] Palladium coordination compounds of σ3λ5-phosphoranes:: First examples of phosphonio-methylene(imino)metallophosphorane [(R3P)(Me3Si)C=P(MLn)=NSiMe3] and phosphonio-methylene(oxo)phosphorane [(R3P)(Me3Si)C=P(=O)NSiMe3] ligands
Konze, WV
Young, VG
Angelici, RJ
ORGANOMETALLICS, 1998, 17 (24) : 5275 - 5286
[33] Arsaalkenes R-As=C(NMe2)2 [R = PhC(O), 4-EtC6H4C(O), 2,4,6-Me3C6H2C(O), tBuC(O), Me3Si]:: Versatile reagents in the chemistry of heterocumulenes
Weber, L
Bayer, P
Braun, T
Stammler, HG
Neumann, B
ORGANOMETALLICS, 2006, 25 (07) : 1786 - 1794
[34] STRUCTURE AND STEREODYNAMICS OF [M(CO)5(P(C6H4ME-O)3)] (M = CR, MO OR W) AND [CR(CO)3(P(C6H4ME-O)3)]
HOWELL, JAS
YATES, PC
PALIN, MG
MCARDLE, P
CUNNINGHAM, D
GOLDSCHMIDT, Z
GOTTLIEB, HE
HEZRONILANGERMAN, D
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1993, (18): : 2775 - 2780
[35] ZUR KENNTNIS DES SILYLTRIAZENS (ME3SI)2N-N=N-C6H5
WIBERG, N
JOO, WC
ZEITSCHRIFT FUR NATURFORSCHUNG PART B-CHEMIE BIOCHEMIE BIOPHYSIK BIOLOGIE UND VERWANDTEN GEBIETE, 1966, B 21 (12): : 1234 - &
[36] CHEMISTRY OF C-TRIMETHYLSILYL-SUBSTITUTED STANNACARBORANES .3. CONVERSION OF CLOSO-1-SN-2-(ME3SI)-3-(R)-2,3-C2B4H4 TO COMMO-1,1'-GE-[2-(ME3SI)-3-(R)-2,3-C2B4H4]2 AND STRUCTURE OF COMMO-1,1'-GE-[2,3-(ME3SI)2-CLOSO-2,3-C2B4H4]2 (R = SIME3, ME, AND H)
ISLAM, MS
SIRIWARDANE, U
HOSMANE, NS
MAGUIRE, JA
DEMEESTER, P
CHU, SSC
ORGANOMETALLICS, 1987, 6 (09) : 1936 - 1940
[37] Synthesis and crystal structures of [Sn{2-[(Me3Si)2C]C5H4N}R] [R = C6H2Pri3,4,6 1 or CH(PPh2)2 2], two novel heteroleptic tin(II) compounds derived from [Sn-{2-[(Me3Si)2C]C5H4N}Cl], and for [{Sn(C6H2Pri3-2,4,6)2}3] 3, a structural redetermination
Cardin, CJ
Cardin, DJ
Constantine, SP
Drew, MGB
Rashid, H
Convery, MA
Fenske, D
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1998, (16): : 2749 - 2756
[38] The 1,3 migration of a methyl group in reactions of the trisyl iodide (Me3Si)3CSi(CD3)2I and related iodides with silver salts in 2,2,2-trifluoroethanol.: Refinement of the mechanism
Eaborn, C
Happer, DAR
Black, JR
Garrity, PM
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 2002, (08): : 1418 - 1422
[39] Solving the 31P{1H} NMR spectrum of (Me3Si)3P7 as B[AC]3 case
Matern, Eberhard
Engelhardt, Michael
Haegele, Gerhard
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 2017, 192 (06) : 727 - 731
[40] Syntheses, structure characterisation and X-ray structures of the complexes Ru3(CO)11L [L = Ph2P(C6H4Me-P), Ph2PC6F5, P(C6H4Cl-p)3, P(3,5-CF3-C6H3)3 and P(C6H4Me-P)3]
bin Shawkataly, Omar
Pankhi, Mohd Aslam A.
Fun, Hoong-Kun
Yeap, Chin Sing
POLYHEDRON, 2010, 29 (13) : 2667 - 2673

← 1 2 3 4 5 →