Synthesis and characterization of rhenium carbonyltrifluoroacetate complexes with phosphites, phosphonites and phosphinites

被引：2

作者：

Bolano, Sandra ^{[1
]}

Bravo, Jorge ^{[1
]}

Castro, Jesus ^{[1
]}

Garcia-Fontan, Soledad ^{[1
]}

Rodriguez, Maria C. ^{[1
]}

机构：

[1] Univ Vigo, Dept Quim Inorgan, E-36310 Vigo, Spain

来源：

POLYHEDRON | 2009年 / 28卷 / 12期

关键词：

Carbonyls; Rhenium; Phosphites; Phosphonites; Phosphinites; HYDRIDE COMPLEXES; CRYSTAL-STRUCTURE; REACTIVITY; LIGANDS; COORDINATION; DERIVATIVES; HEME; CO;

D O I：

10.1016/j.poly.2009.04.045

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The rhenium(I) complexes [Re(O2CCF3)CO)(3)(L)] (1) and [Re(O2CCF3)(CO)(2)LL'] (L = Ph2POCH2CH2OPPh2: L' = PPhn(OR)(3-n); R = Me, Et; n = 0-2) (2a-f) have been synthesised by the reaction of the parent bromo derivatives with AgO2CCF3. These compounds have been characterized by microanalysis, IR, NMR, mass spectrometry and, in the cases of 1 and 2a, by X-ray diffraction. The metal is in a distorted octahedral environment with the trifluoroacetate ligand acting in a monodentate manner. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：2431 / 2435

页数：5

共 50 条

[21] Synthesis and physicochemical characterization of rhenium(V) complexes with bisbenzoylthiosemicarbazones
Gagieva, SC
Gutnova, NA
Tsaloev, AT
Khubulov, AB
Arutyunyants, AA
Gallimov, YB
[J]. RUSSIAN JOURNAL OF INORGANIC CHEMISTRY, 2003, 48 (05) : 687 - 692
[22] SYNTHESIS AND CHARACTERIZATION OF RHENIUM(VII) OXIDE COMPLEXES OF PHENOTHIAZINES
GOWDA, NMM
PHYU, HP
ACKERSON, BE
[J]. TRANSITION METAL CHEMISTRY, 1993, 18 (01) : 64 - 68
[23] A NEW METHOD OF SYNTHESIS OF CELLULOSE PHOSPHITES AND PHOSPHINITES - THEIR USE AS LIGANDS IN METAL-COMPLEX CATALYSIS
MISHINA, VY
GRACHEV, MK
TELESHEV, AT
NIFANTEV, EE
[J]. VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B, 1995, 37 (04): : 713 - 714
[24] SYNTHESIS AND ANTIOXIDATIVE EFFICIENCY OF ORGANIC PHOSPHITES AND PHOSPHONITES WITH 2.2.6.6-TETRAMETHYLPIPERIDIN-4-YL GROUPS
HAHNER, U
HABICHER, WD
CHMELA, S
[J]. POLYMER DEGRADATION AND STABILITY, 1993, 41 (02) : 197 - 203
[25] ACTION DES PHOSPHITES SODES DES PHOSPHONITES SODES + DES PHOSPHINITES SUR LES CETONES HALOGENEES PRISES SOUS FORME DE CETALS OU DETHERS ENOLIQUES
STURTZ, G
[J]. BULLETIN DE LA SOCIETE CHIMIQUE DE FRANCE, 1964, (09): : 2340 - &
[26] SYNTHESIS AND CHARACTERIZATION OF RHENIUM DIHYDROGEN COMPLEXES CONTAINING ISONITRILE COLIGANDS
HEINEKEY, DM
VOGES, MS
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 209 : 500 - INOR
[27] SYNTHESIS AND CHARACTERIZATION OF GALLIUM, INDIUM, RHENIUM AND TECHNETIUM THIOLATE COMPLEXES
ROSE, DJ
CHANG, YD
CHEN, Q
KETTLER, PB
NICHOLSON, T
ZUBIETA, J
[J]. ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1995, 210 : 491 - INOR
[28] Synthesis, characterization and crystal structures of rhenium(V) complexes with diphosphines
Kremer, C
Rivero, M
Kremer, E
Suescun, L
Mombrú, AW
Mariezcurrena, R
Domínguez, S
Mederos, A
Midollini, S
Castiñeiras, A
[J]. INORGANICA CHIMICA ACTA, 1999, 294 (01) : 47 - 55
[29] Work-up-free deprotection of borane complexes of phosphines, phosphites, and phosphinites with polymer-supported amines
Sayalero, Sonia
Pericas, Miquel A.
[J]. SYNLETT, 2006, (16) : 2585 - 2588
[30] CATALYTIC ENANTIOSELECTIVE HYDROSILYLATION OF AROMATIC KETONES USING RHODIUM COMPLEXES OF TADDOL-DERIVED CYCLIC PHOSPHONITES AND PHOSPHITES
SAKAKI, J
SCHWEIZER, WB
SEEBACH, D
[J]. HELVETICA CHIMICA ACTA, 1993, 76 (07) : 2654 - 2665

← 1 2 3 4 5 →