SYNTHESIS AND CHARACTERIZATION OF RHENIUM(VII) OXIDE COMPLEXES OF PHENOTHIAZINES

被引:10
|
作者
GOWDA, NMM
PHYU, HP
ACKERSON, BE
机构
[1] Department of Chemistry, Western Illinois University, Macomb, 61455, IL
关键词
D O I
10.1007/BF00136053
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Five complexes of rhenium(VII) oxide with N-alkylphenothiazines have been synthesized and characterized on the basis of elemental analyses, molar conductances, and u.v.-vis., i.r. and n.m.r. spectral data. The molecular formulas of the new ionic complexes are: [ReO3(PTZ)2(H2O)]-[ReO4], PTZ = chlorpromazine, promethazine or ethopropazine; [ReO3(TF)(H2O)][ReO4], TF = trifluoperazine; and [ReO3(TR)3][ReO4(H2O)2] . H2O, TR = thioridazine. Tentative structures have been proposed.
引用
收藏
页码:64 / 68
页数:5
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