Synthesis and characterization of rhenium carbonyltrifluoroacetate complexes with phosphites, phosphonites and phosphinites

被引：2

作者：

Bolano, Sandra ^{[1
]}

Bravo, Jorge ^{[1
]}

Castro, Jesus ^{[1
]}

Garcia-Fontan, Soledad ^{[1
]}

Rodriguez, Maria C. ^{[1
]}

机构：

[1] Univ Vigo, Dept Quim Inorgan, E-36310 Vigo, Spain

来源：

POLYHEDRON | 2009年 / 28卷 / 12期

关键词：

Carbonyls; Rhenium; Phosphites; Phosphonites; Phosphinites; HYDRIDE COMPLEXES; CRYSTAL-STRUCTURE; REACTIVITY; LIGANDS; COORDINATION; DERIVATIVES; HEME; CO;

D O I：

10.1016/j.poly.2009.04.045

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The rhenium(I) complexes [Re(O2CCF3)CO)(3)(L)] (1) and [Re(O2CCF3)(CO)(2)LL'] (L = Ph2POCH2CH2OPPh2: L' = PPhn(OR)(3-n); R = Me, Et; n = 0-2) (2a-f) have been synthesised by the reaction of the parent bromo derivatives with AgO2CCF3. These compounds have been characterized by microanalysis, IR, NMR, mass spectrometry and, in the cases of 1 and 2a, by X-ray diffraction. The metal is in a distorted octahedral environment with the trifluoroacetate ligand acting in a monodentate manner. (C) 2009 Elsevier Ltd. All rights reserved.

引用

页码：2431 / 2435

页数：5

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